stainless steel; oxygen; isobutyraldehyde in carbon dioxide T=55°C; Oxidation; Ring cleavage; P=142514 Torr; 18 h; Title compound not separated from byproducts.;
参考文献
Chemistry - A European Journal, , vol. 6, # 11 p. 2011 - 2015
Bulletin of the Academy of Sciences of the USSR, Division of Chemical Science (English Translation), , vol. 40, # 5.1 p. 945 - 950
Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, , # 5 p. 1063 - 1069
ammonium cerium(IV) nitrate in acetone anh. (NH4)2Ce(NO3)6 was added portionwise to a stirred soln. of (C8H8)Fe(CO)3 in anh. acetone (after 50 min and 70 min), after 100 min of reaction addn. of H2O, mixture was extracted with CH2Cl2 (4 times), extract was dried (MgSO4), solvent evaporation;; filtration through a short column of silica gel; white crystals with m.p. 54-55°C were obtained;;
参考文献
Bonfantini, Edia; Metral, Jean-Luc; Vogel, Pierre
Helvetica Chimica Acta, 1987 , vol. 70, p. 1791 - 1797
