N-对甲苯磺酰基-2-碘苯胺合成路线 （共 16 条）
反应条件
trans-di(μ-acetato)bis[o-(di-o-tolylphosphino)benzyl]dipalladium(II); caesium carbonate in N,N-dimethyl-formamide
12 h; Inert atmosphere;
参考文献
Rixson, James E.; Chaloner, Thomas; Heath, Charles H.; Tietze, Lutz F.; Stewart, Scott G.
European Journal of Organic Chemistry, 2012 , # 3 p. 544 - 558
反应条件
tetrakis(triphenylphosphine) palladium(0); triethylamine in N,N-dimethyl-formamide
T=20 - 80°C; Tsuji-Trost/Heck reaction; 17 h; Inert atmosphere;
参考文献
Rixson, James E.; Chaloner, Thomas; Heath, Charles H.; Tietze, Lutz F.; Stewart, Scott G.
European Journal of Organic Chemistry, 2012 , # 3 p. 544 - 558
反应条件
1: tetrakis(triphenylphosphine) palladium(0); tetra(n-butyl)ammonium hydrogensulfate; caesium carbonate / N,N-dimethyl-formamide; toluene / 18 h / 60 °C / Inert atmosphere
2: palladium diacetate; caesium carbonate; triphenylphosphine / N,N-dimethyl-formamide / 12 h / 40 °C / Inert atmosphere
View Scheme
参考文献
Rixson, James E.; Chaloner, Thomas; Heath, Charles H.; Tietze, Lutz F.; Stewart, Scott G.
European Journal of Organic Chemistry, 2012 , # 3 p. 544 - 558
反应条件
copper(l) iodide; triethylamine; bis-triphenylphosphine-palladium(II) chloride in tetrahydrofuran
T=20°C; Sonogashira cross-coupling;
参考文献
Martinez-Esperon, M. Fernanda; Rodriguez, David; Castedo, Luis; Saa, Carlos
Tetrahedron, 2008 , vol. 64, # 17 p. 3674 - 3686
反应条件
potassium carbonate in N,N-dimethyl-formamide
48 h;
参考文献
Bressy, Cyril; Alberico, Dino; Lautens, Mark
Journal of the American Chemical Society, 2005 , vol. 127, # 38 p. 13148 - 13149
反应条件
caesium carbonate; copper(I) bromide in dimethyl sulfoxide
T=80°C; 24 h;
参考文献
Pi, Sha-Sha; Zhang, Xing-Guo; Tang, Ri-Yuan; Li, Jin-Heng
Synlett, 2009 , # 18 p. 3032 - 3036
