1: 5-Bromo-2-methyl-pent-2-ene With magnesium in tetrahydrofuran 4 h; Inert atmosphereReflux; 2: 2-isopropoxy-4,4,5,5-tetramethyl-1,3,2-dioxaborolane in tetrahydrofuran T=-78 - 20°C; Inert atmosphere;
参考文献
Aggarwal, Varinder K.; Ball, Liam T.; Carobene, Simon; Connelly, Rickki L.; Hesse, Matthew J.; Partridge, Benjamin M.; Roth, Philippe; Thomas, Stephen P.; Webster, Matthew P.
Chemical Communications, 2012 , vol. 48, # 74 p. 9230 - 9232
1: 2-bromofuran With n-butyllithium in tetrahydrofuran; hexane T=-78°C; 2 h; 2: 2-isopropoxy-4,4,5,5-tetramethyl-1,3,2-dioxaborolane in tetrahydrofuran; hexane T=-78 - 20°C; 3: With methanol in tetrahydrofuran; hexane
1: furan With n-butyllithium in tetrahydrofuran; hexane T=0 - 23°C; Inert atmosphere; 2: 2-isopropoxy-4,4,5,5-tetramethyl-1,3,2-dioxaborolane in tetrahydrofuran; hexane T=-78 - 23°C; Inert atmosphere;
参考文献
Ebner, David C.; Bagdanoff, Jeffrey T.; Ferreira, Eric M.; McFadden, Ryan M.; Caspi, Daniel D.; Trend, Raissa M.; Stoltz, Brian M.
Chemistry - A European Journal, 2009 , vol. 15, # 47 p. 12978 - 12992
