乳化剂MOA-3，7，9，15，20合成路线 （共 17 条）
反应条件
sulfuric acid
T=100°C;
参考文献
Shinkai, Seiji; Hamada, Hisatake; Kuroda, Hideo; Manabe, Osamu
Journal of Organic Chemistry, 1981 , vol. 46, # 11 p. 2333 - 2338
反应条件
trichlorophosphate in N,N-dimethyl-formamide
参考文献
Do, Quyen; Thi Mai, Huong Doan; Gaslonde, Thomas; Pfeiffer, Bruno; Leonce, Stephane; Pierre, Alain; Michel, Sylvie; Tillequin, Francois; Dufat, Hanh
European Journal of Medicinal Chemistry, 2008 , vol. 43, # 12 p. 2677 - 2687
反应条件
1: sodium amide / tetrahydrofuran / 16 h / 50 °C
2: phosphorous pentoxide; phosphoric acid / 16 h / 110 °C
View Scheme
参考文献
Deiters, Emmanuel; Gumy, Frederic; Buenzli, Jean-Claude G.
European Journal of Inorganic Chemistry, 2010 , # 18 p. 2723 - 2734
反应条件
1: sodium amide / tetrahydrofuran / 16 h / 50 °C
2: phosphorous pentoxide; phosphoric acid / 16 h / 110 °C
View Scheme
参考文献
Deiters, Emmanuel; Gumy, Frederic; Buenzli, Jean-Claude G.
European Journal of Inorganic Chemistry, 2010 , # 18 p. 2723 - 2734
反应条件
phosphorous pentoxide; phosphoric acid
T=110°C; Friedel Crafts acylation; 16 h;
参考文献
Deiters, Emmanuel; Gumy, Frederic; Buenzli, Jean-Claude G.
European Journal of Inorganic Chemistry, 2010 , # 18 p. 2723 - 2734
反应条件
1: 40 percent / Cu
2: 65 percent / concd. H2SO4 / 100 °C
View Scheme
参考文献
Shinkai, Seiji; Hamada, Hisatake; Kuroda, Hideo; Manabe, Osamu
Journal of Organic Chemistry, 1981 , vol. 46, # 11 p. 2333 - 2338
反应条件
1: 1.) magnesium / 1.) ether, 2.) ice-bath, 4 h
2: 1.) conc. HCl, sodium nitrite, 2.) sodium azide, sodium acetate / 1.) acetic acid, water, below 5 deg C
3: 94 percent / various solvent(s) / 3 h / Heating
4: 29 percent / various solvent(s) / 6 h / Heating
View Scheme
参考文献
Hawkins, David G.; Meth-Cohn, Otto
Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 1983 , p. 2077 - 2087
反应条件
1: 1.) conc. HCl, sodium nitrite, 2.) sodium azide, sodium acetate / 1.) acetic acid, water, below 5 deg C
2: 94 percent / various solvent(s) / 3 h / Heating
3: 29 percent / various solvent(s) / 6 h / Heating
View Scheme
参考文献
Hawkins, David G.; Meth-Cohn, Otto
Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 1983 , p. 2077 - 2087
反应条件
1: 91 percent
2: 1.) magnesium / 1.) ether, 2.) ice-bath, 4 h
3: 1.) conc. HCl, sodium nitrite, 2.) sodium azide, sodium acetate / 1.) acetic acid, water, below 5 deg C
4: 94 percent / various solvent(s) / 3 h / Heating
5: 29 percent / various solvent(s) / 6 h / Heating
View Scheme
参考文献
Hawkins, David G.; Meth-Cohn, Otto
Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 1983 , p. 2077 - 2087
反应条件
1: 40 percent / Cu
2: 65 percent / concd. H2SO4 / 100 °C
View Scheme
参考文献
Shinkai, Seiji; Hamada, Hisatake; Kuroda, Hideo; Manabe, Osamu
Journal of Organic Chemistry, 1981 , vol. 46, # 11 p. 2333 - 2338
