in neat (no solvent) 200 - 420°C, decompn. of Na2C2O4 to Na2CO3 and CO, disproportionation of some CO to CO2 and C, the composition of the products is depending on the temperature;;
in neat (no solvent, solid phase) byproducts: CO, CO2; thermal decomposition of Na2C2O4 in He, Ar, N2, CO and CO2 atmosphere, the heating rate was 6 deg/min; detd. by XRD and IR;
参考文献
Gorski, A.; Krasnicka, A. D.
Journal of Thermal Analysis, 1987 , vol. 32, p. 1229 - 1242
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反应条件
in solid React. mixt. is prepared by grinding (mole ratio 1:2), heating in temp. range of 425-475°C.; X-ray powder diffraction;
参考文献
Suba; Udupa
Journal of thermal analysis, 1989 , vol. 35, # 4 p. 1197 - 1203
