in chloroform a solution of two equivalents of halogen added dropwise to a solution of organocobaloxime at room temperature under nitrogen in the dark; NMR, UV;
oxygen; sodium bromide; anhydrous cobalt diacetate T=64.9°C; variation of catalyst system concentration, kinetic control and diffusion control; Rate constant;
参考文献
J. Gen. Chem. USSR (Engl. Transl.), , vol. 58, # 6 p. 1336 - 1340,1188 - 1192
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反应条件
in chloroform reaction of solution of Co-compound in dry chloroform with chloroformic soln. of Br2 (2 moles) under N2 at room temp.;
