4-甲基-N-苯基苯胺合成路线 （共 140 条）
反应条件
BrettPhos Palladacycle; sodium t-butanolate; dicyclohexyl(2',6'-diisopropoxy-[1,1'-biphenyl]-2-yl)phosphine in 1,4-dioxane T=110°C; 24 h; Inert atmosphere;
参考文献
EVONIK DEGUSSA GMBH; INSTITUTE OF ORGANIC CHEMISTRY POLISH ACADEMY OF SCIENCES; AZAP, Cengiz; WOLF, Dorit; ABBENHUIS, Hendrikus Cornelis Louis; GERRITSEN, Gijsbert; GRELA, Karol; WILTING, Jos B.M.; LESZCZYNSKA, Kinga; CZABAN, Justyna; WOJTASIEWICZ, Anna
Patent: WO2011/107417 A1, 2011 ;
Location in patent: Page/Page column 25-26 ;
反应条件
tri-tert-butyl phosphine; sodium t-butanolate; tris-(dibenzylideneacetone)dipalladium(0) in toluene T=20°C; 18 h;
参考文献
The Regents of the University of California
Patent: US2003/229082 A1, 2003 ;
Location in patent: Page 16 ;
反应条件
copper acetylacetonate; potassium hydroxide in glycerol T=100°C; 15 h; Inert atmosphereGreen chemistry;
参考文献
Khatri, Praveen K.; Jain, Suman L.
Tetrahedron Letters, 2013 , vol. 54, # 21 p. 2740 - 2743
反应条件
C29H25CuIN3OPPd; sodium t-butanolate in toluene T=40°C; 24 h;
参考文献
Tsukada, Naofumi; Ohnishi, Nozomi; Aono, Shiori; Takahashi, Fusako
Organometallics, 2012 , vol. 31, # 21 p. 7336 - 7338
反应条件
polystyrene-supported Cu(I) catalyst in methanol T=40°C; Ullmann coupling; 15 h; Inert atmosphere;
参考文献
Islam; Mondal, Sanchita; Mondal, Paramita; Roy, Anupam Singha; Tuhina, Kazi; Mobarok, Manir
Inorganic Chemistry Communications, 2011 , vol. 14, # 9 p. 1352 - 1357
反应条件
sodium t-butanolate; palladium diacetate; CyPF-t-Bu in ethylene glycol dimethyl ether T=100°C; 24 h;
参考文献
Fors, Brett P.; Buchwald, Stephen L.
Journal of the American Chemical Society, 2010 , vol. 132, # 45 p. 15914 - 15917
反应条件
C21H16CuN2O2; potassium carbonate in water T=28°C; Chan-Lam Coupling; 12 h;
参考文献
Gogoi, Ankur; Sarmah, Gayatri; Dewan, Anindita; Bora, Utpal
Tetrahedron Letters, 2014 , vol. 55, # 1 p. 31 - 35
反应条件
(R,R(Fc))-1-diphenylphosphino-2-(1-di-tert-butylphosphinoethyl)ferrocene; bis(dibenzylideneacetone)-palladium(0); sodium t-butanolate in toluene T=110°C; 16 h; other amines; other aryl halides and tosylates; var. chelating alkylphosphines, var. time, var. temp., further solvent; MechanismProduct distribution;
参考文献
Arentsen, Katherine; Caddick, Stephen; Cloke, F. Geoffrey N.
Tetrahedron, 2005 , vol. 61, # 41 p. 9710 - 9715
反应条件
2-(di-tert-butylphosphino)-2'-isopropoxy-1,1'-binaphthyl; potassium phosphate; palladium diacetate; 3,4,5-trimethoxyphenylboronic acid in butan-1-ol T=110°C; 15 h; Inert atmosphere;
参考文献
Xie, Xiaomin; Ni, Gang; Ma, Fangfang; Ding, Lina; Xu, Sheng; Zhang, Zhaoguo
Synlett, 2011 , # 7 p. 955 - 958
反应条件
tetrabutylammomium bromide; oxygen; palladium diacetate in dimethyl sulfoxide; toluene T=90°C; P=760.051 Torr; 12 h; Schlenk techniqueMolecular sieveInert atmosphere; Reagent/catalystSolvent;
参考文献
Hajra, Alakananda; Wei, Ye; Yoshikai, Naohiko
Organic Letters, 2012 , vol. 14, # 21 p. 5488 - 5491,4
