4,4’-二甲基二苯硫醚合成路线 （共 108 条）
反应条件
in N,N-dimethyl-formamide
T=100°C; 10 h;
参考文献
Huang; Zhu; Xu
Synthetic Communications, 2001 , vol. 31, # 18 p. 2823 - 2828
反应条件
diisobutylaluminum hydride in hexane; toluene
52 h; Heating;
参考文献
Desando, M. A.; Walker, S.; Baarschers, W.H.
Journal of Chemical Physics, 1980 , vol. 73, # 7 p. 3460 - 3466
反应条件
1: p-methylphenylboronic acid With potassium ethylxanthate; copper(l) chloride in methanol
3 h; Inert atmosphereReflux;
2: p-methylphenylboronic acid With potassium hydroxide in methanol
5 h; Inert atmosphereReflux;
参考文献
Wang, Liang; Zhou, Wei-You; Chen, Sheng-Chun; He, Ming-Yang; Chen, Qun
Synlett, 2011 , # 20 art. no. W18411ST, p. 3041 - 3045
反应条件
potassium carbonate; thiophenol; zinc; 1,1'-bis-(diphenylphosphino)ferrocene; niobium bromide in N,N-dimethyl-formamide
T=60°C; 5 h; Title compound not separated from byproducts;
参考文献
Takagi, Kentaro
Chemistry Letters, 1987 , p. 2221 - 2224
反应条件
bromobenzene; potassium carbonate; zinc; 1,1'-bis-(diphenylphosphino)ferrocene; niobium bromide in N,N-dimethyl-formamide
T=60°C; 2 h; Title compound not separated from byproducts;
参考文献
Takagi, Kentaro
Chemistry Letters, 1987 , p. 2221 - 2224
反应条件
1: 3.1 mmol / potassium tert-butoxide / dimethylsulfoxide / 15 h / 25 °C / Irradiation
2: 0.6 mmol / potassium tert-butoxide / dimethylformamide / 15 h / 25 °C / Irradiation
3: 73 percent / sodium isobutoxide / tetrakis(triphenylphosphine)palladium(0) / various solvent(s) / 8 h / Heating
View Scheme
参考文献
Cheng, Carlos; Stock, Leon M.
Journal of Organic Chemistry, 1991 , vol. 56, # 7 p. 2436 - 2443
反应条件
1: 0.4 mmol / potassium tert-butoxide / dimethylsulfoxide / 15 h / 25 °C / Irradiation
2: 0.6 mmol / potassium tert-butoxide / dimethylformamide / 15 h / 25 °C / Irradiation
3: 73 percent / sodium isobutoxide / tetrakis(triphenylphosphine)palladium(0) / various solvent(s) / 8 h / Heating
View Scheme
参考文献
Cheng, Carlos; Stock, Leon M.
Journal of Organic Chemistry, 1991 , vol. 56, # 7 p. 2436 - 2443
反应条件
1: 0.6 mmol / potassium tert-butoxide / dimethylformamide / 15 h / 25 °C / Irradiation
2: 73 percent / sodium isobutoxide / tetrakis(triphenylphosphine)palladium(0) / various solvent(s) / 8 h / Heating
View Scheme
参考文献
Cheng, Carlos; Stock, Leon M.
Journal of Organic Chemistry, 1991 , vol. 56, # 7 p. 2436 - 2443
反应条件
potassium carbonate; zinc; 1,1'-bis-(diphenylphosphino)ferrocene; niobium bromide in N,N-dimethyl-formamide
T=60°C; 5 h; Title compound not separated from byproducts;
参考文献
Takagi, Kentaro
Chemistry Letters, 1987 , p. 2221 - 2224
反应条件
potassium carbonate; zinc; 1,1'-bis-(diphenylphosphino)ferrocene; niobium bromide in N,N-dimethyl-formamide
T=60°C; 2 h; Title compound not separated from byproducts;
参考文献
Takagi, Kentaro
Chemistry Letters, 1987 , p. 2221 - 2224
