triphenylphosphine; tetrakis(triphenylphosphine) palladium(0) in tetrahydrofuran T=60°C; 15 h; Heating; Yield given. Yields of byproduct given;
参考文献
Ono, Noburu; Hamamoto, Isami; Kaji, Aritsune
Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 1986 , p. 1439 - 1444
dichloro bis(acetonitrile) palladium(II); triethylamine in tetrahydrofuran multistep reaction: 1.) -78 deg C, 2.) -60 deg C -> room temperature; palladium-assisted alkylation of various olefin with carbanions accompanied by reductive or β-elimination isolation procedure; stereo- and regioselectivity; Product distribution;
参考文献
Journal of the American Chemical Society, , vol. 102, p. 4973
bis(η3-allyl-μ-chloropalladium(II)); triphenylphosphine in tetrahydrofuran
T=0°C; 12 h; other catalyst, temperature, time; also in the presence of various alkali metal halides; also with other nucleofiles; Product distribution;
参考文献
Kawatsura, Motoi; Uozumi, Yasuhiro; Hayashi, Tamio
Chemical Communications, 1998 , # 2 p. 217 - 218
