(R)-(+)-2-(Diphenylphosphino)-2′-methoxy-1,1′-binaphthyl; bis(η3-allyl-μ-chloropalladium(II)) in tetrahydrofuran
T=-30°C; 6 h; other temperature, various ratios ligand:Pd; also with achiral ligands; Product distribution;
参考文献
Hayashi, Tamio; Kawatsura, Motoi; Uozumi, Yasuhiro
Chemical Communications, 1997 , # 6 p. 561 - 562
dichloro bis(acetonitrile) palladium(II); triethylamine in tetrahydrofuran
multistep reaction: 1.) -78 deg C, 2.) -60 deg C -> room temperature; palladium-assisted alkylation of various olefin with carbanions accompanied by reductive or β-elimination isolation procedure; stereo- and regioselectivity; Product distribution;
参考文献
Hegedus,L.S.; Williams,R.E.; Mcguire,M.A.
Journal of the American Chemical Society, 1980 , vol. 102, p. 4973
