tetrabutylammomium bromide; oxygen; palladium diacetate in dimethyl sulfoxide T=90°C; P=760.051 Torr; 12 h; Schlenk techniqueMolecular sieveInert atmosphere;

1: p-toluidine With n-butyllithium; ZnCl2*TMEDA in tetrahydrofuran; hexane T=0 - 20°C; 0.5 h; Inert atmosphereSchlenk technique; 2: 3-methylphenylmagnesium bromide With N,N'-dimethyl-N,N'-propyleneurea; bis(acetylacetonate)nickel(II); 1,2-dichloro-2-methylpropane in tetrahydrofuran; hexane T=0 - 20°C; 3 h; Inert atmosphereSchlenk technique;

bis(η3-allyl-μ-chloropalladium(II)); potassium tert-butylate; SIDip*HCl in 1,4-dioxane T=100°C; 1.5 h; Inert atmosphere;

1: With caesium carbonate; chloroacetyl chloride in N,N-dimethyl-formamide T=20°C; Smiles rearrangement; 0.5 h; 2: in N,N-dimethyl-formamide T=150°C; Smiles rearrangement; Microwave irradiation;

bis-triphenylphosphine-palladium(II) chloride; OHC6H4CHNC6H3F2; sodium t-butanolate in o-xylene 12 h; Inert atmosphereSchlenk techniqueReflux;

boron trifluoride diethyl etherate T=60°C; 12 h;

soda lime T=335 - 340°C; 1-stdg. Erhitzen auf 370grad;

copper; potassium carbonate; potassium iodide