1: With Rh2(OAc)4; 1,3-bis(2,4,6-trimethylphenyl)imidazolinium chloride; sodium t-butanolate; tri-cyclo-hexyl-phosphine in toluene T=80°C; 2: With water Acidic conditions;
参考文献
Kim, Min; Kwak, Jaesung; Chang, Sukbok
Angewandte Chemie - International Edition, 2009 , vol. 48, # 47 p. 8935 - 8939
carbon monoxide in diethyl ether High Pressure; under dried N2; addn. of N-methylbenzimine at 25°C to a soln. of W-complex (CO-pressure: 50 atm); stirring for 2 d at room temp., then for 1-2 h at 80-100°C; vac.-evapn. until dryness; residue dissolved in petroleum ether/ether; chromy. (silica gel/petroleum ether/ether); recrystn. from petroleum ether; elem. anal.;
参考文献
Journal of Organometallic Chemistry, , vol. 373, p. 203 - 220
