2,5-二氯-2,5-二甲基己烷合成路线 （共 77 条）
反应条件
T=255 - 270°C; P=12 - 20 Torr; bei langsamer Destillation;
参考文献
Staudinger; Ruzicka
Helvetica Chimica Acta, 1924 , vol. 7, p. 385
反应条件
aluminium trichloride in dichloromethane T=0°C; 0.333333 h;
参考文献
Eyrolles, Laurence; Kagechika, Hiroyuki; Kawachi, Emiko; Fukasawa, Hiroshi; Iijima, Tohru; et al.
Journal of Medicinal Chemistry, 1994 , vol. 37, # 10 p. 1508 - 1517
反应条件
1: AlCl3 / CH2Cl2 2: HNO3 View Scheme
参考文献
Kagechika, Hiroyuki; Kawachi, Emiko; Hashimoto, Yuichi; Himi, Toshiyuki; Shudo, Koichi
Journal of Medicinal Chemistry, 1988 , vol. 31, # 11 p. 2182 - 2192
反应条件
1: soda lime / 255 - 270 °C / 12 - 20 Torr 2: 100 °C / im Rohr und Verseifen des Reaktionsprodukts mit alkoh. Kalilauge View Scheme
参考文献
Staudinger; Ruzicka
Helvetica Chimica Acta, 1924 , vol. 7, p. 385
→
22306-30-51,1,4,4,5,5,8,8-八甲基-1,2,3,4,5,6,7,8-八氢蒽+
反应条件
aluminium trichloride in pentane 0.666667 h; Ambient temperature;
参考文献
Journal of Organic Chemistry, , vol. 25, p. 708 - 711
反应条件
1: AlCl3 2: aq. NaOH, KMnO4 / pyridine View Scheme
参考文献
Baba, Masanori; Hashimoto, Yuichi
Patent: US2011/172185 A1, 2011 ;
反应条件
1: 99 percent / AlCl3 / CH2Cl2 / 20 °C 2: 85 percent / Br2; AlCl3 / CH2Cl2 View Scheme
参考文献
Journal of Organic Chemistry, , vol. 66, # 17 p. 5772 - 5782
反应条件
aluminium trichloride
参考文献
Tetrahedron Letters, , vol. 38, # 46 p. 8067 - 8070
反应条件
aluminium chloride in methanol
反应条件
1: hydrogenchloride / AlCl3 / toluene 2: AlCl3 / ethyl acetate; (2S)-N-methyl-1-phenylpropan-2-amine hydrate View Scheme
参考文献
Reinnervate Limited
Patent: US8293803 B2, 2012 ;
