2,5-二氯-2,5-二甲基己烷 合成路线 （共 77 条）
反应条件
1: 91 percent / AlCl3 / CH2Cl2 2: 50 percent / HNO3; H2SO4 / -10 °C 3: 48 percent / H2 / Pd/C / ethanol View Scheme
参考文献
Kagechika, Hiroyuki; Kawachi, Emiko; Hashimoto, Yuichi; Himi, Toshiyuki; Shudo, Koichi
反应条件
1: FeCl3
2: AlCl3
View Scheme
参考文献
Wood,T.F. et al.
反应条件
1.1: AlCl3, aluminium chloride / dichloromethane / |Reflux
2.1: palladium dichloride; copper(l) iodide; triethylamine / methanol / 20 °C / |Sonication
3.1: sodium hydride / toluene / |Reflux
3.2: 20 °C
4.1: n-butyllithium / tetrahydrofuran / -78 °C
4.2: 20 °C
5.1: tetrahydrofuran; hexane / 0.17 h / 0 - 20 °C / |Inert atmosphere
5.2: 2 h / |Reflux; |Inert atmosphere
6.1: tetrahydrofuran; hexane / 0.17 h / -78 °C / |Inert atmosphere
7.1: tetrahydrofuran; hexane / 0.5 h / |Inert atmosphere
8.1: Cl2Ni(1,2-bis(diphenylphosphino)ethane) / tetrahydrofuran / 2.5 h / |Inert atmosphere; |Reflux
View Scheme
参考文献
Guerrero Jr., Palimecio G.; De Oliveira, Paulo R.; Baroni, Adriano C.M.; Marques, Francisco A.; Labes, Ricardo; Hurtado, Gabriela R.; Dabdoub, Miguel J.
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反应条件
77308-48-6 1,1,4,4,7,7,10,10-八甲基-2,3,4,7,8,9,10,12-八氢-1H-二苯并[b,h]芴
反应条件
aluminium trichloride in nitromethane
19 h;
参考文献
Irwin, Levi J.; Reibenspies, Joseph H.; Miller, Stephen A.
反应条件
1: FeCl3
2: AlCl3; 1,2-dichloro-ethane
View Scheme
参考文献
Wood,T.F. et al.
反应条件
tin(IV) chloride; Petroleum ether
参考文献
Bruson; Kroeger
反应条件
1: 91 percent / aluminum chloride / CH2Cl2 / 0.5 h / 20 °C
2: 78 percent / aq. (NH4)2Ce(NO3)6 / acetic acid / 1 h / 20 °C
View Scheme
参考文献
Dawson; Hobbs; Derdzinski; Chao; Frenking; Loew; Jetten; Napoli; Williams; Sani; Wille Jr.; Schiff
参考文献
Wood,T.F. et al.
反应条件
1: 83 percent / AlCl3 / CH2Cl2
2: 78 percent / AlCl3 / hexane; CH2Cl2 / Heating
3: KOH / dimethylsulfoxide
View Scheme
参考文献
Koch; Dardashti; Hebert; White; Croston; Flatten; Heyman; Nadzan
反应条件
1: FeCl3
2: aqueous HCl; concentrated H2SO4
3: aqueous hexamethylenetetramine
View Scheme
参考文献
Wood,T.F. et al.
