(3E,7E)-4,8,12-三甲基十三-1,3,7,11-四烯合成路线 （共 16 条）
反应条件
1: aq. HBr / 0.75 h / Ambient temperature
2: KOH
View Scheme
参考文献
Julia,M. et al.
Bulletin de la Societe Chimique de France, 1960 , p. 1072 - 1079
反应条件
yeast WAT11 strain transfected with full-length CYP82G1 cDNA cloned into modified YEp352 gateway vector
Enzymatic reaction;
参考文献
Lee, Sungbeom; Badieyan, Somayesadat; Bevan, David R.; Herde, Marco; Gatz, Christiane; Tholl, Dorothea
Proceedings of the National Academy of Sciences of the United States of America, 2010 , vol. 107, # 49 p. 21205 - 21210
反应条件
Yield given. Yields of byproduct given;
参考文献
Maurer, Bruno; Hauser, Arnold; Froidevaux, Jean-Claude
Tetrahedron Letters, 1986 , vol. 27, # 19 p. 2111 - 2112
参考文献
Maurer, Bruno; Hauser, Arnold; Froidevaux, Jean-Claude
Tetrahedron Letters, 1986 , vol. 27, # 19 p. 2111 - 2112
反应条件
cytochrome P450 monooxygenase of Arabidopsis CYP82 family CYP82G1, recombinant
Enzymatic reaction; Kinetics;
参考文献
Lee, Sungbeom; Badieyan, Somayesadat; Bevan, David R.; Herde, Marco; Gatz, Christiane; Tholl, Dorothea
Proceedings of the National Academy of Sciences of the United States of America, 2010 , vol. 107, # 49 p. 21205 - 21210
反应条件
1: 1.) BH3, 2-methyl-2-butene, 2.) 3 N NaOH, 30percent H2O2 / 1.) THF, 0 deg C, 2 h; room temperature, 12 h, 2.) -10 deg C to room temperature, 3 h
2: 97 percent / PPh3, Br2, pyridine / CH2Cl2 / 1.5 h / 0 °C
View Scheme
参考文献
Dodd, Dharmpal S.; Oehlschlager, Allan C.
Journal of Organic Chemistry, 1992 , vol. 57, # 10 p. 2794 - 2803
