3-[(三甲基硅烷基)氧基]-2-环己烯-1-酮合成路线 （共 15 条）
反应条件
1: 52 percent / ZnCl2 / CH2Cl2; diethyl ether / 1 h / 0 °C 2: 72 percent / NH2-NH2 / ethanol / 4 h / Ambient temperature 3: 82 percent / NaBH4 / ethanol / 4 h / 40 °C 4: 80 percent / p-toluenesulfonic acid / 10percent Pd/C / dioxane / 8 h / 100 °C View Scheme
参考文献
Croce, Piero Dalla; Rosa, Concetta La
Synthesis, 1984 , # 11 p. 982 - 983
反应条件
in diethyl ether 24 h;
参考文献
Zhou, Yong Fan; Huang, Nai Zheng
Synthetic Communications, 1982 , vol. 12, # 10 p. 795 - 800
反应条件
methanesulfonic acid; tetrabutyl ammonium fluoride 1) THF, reflux, 5 d; 2) ClCH2CH2Cl, 24 h, reflux; Yield given. Multistep reaction. Yields of byproduct given;
参考文献
Helvetica Chimica Acta, , vol. 67, # 7 p. 1755 - 1766
反应条件
methanesulfonic acid; tetrabutyl ammonium fluoride 1) THF, reflux, 7 d; 2) ClCH2CH2Cl, 24 h, reflux; Yield given. Multistep reaction. Yields of byproduct given;
参考文献
Duthaler; Wegmann
Helvetica Chimica Acta, 1984 , vol. 67, # 7 p. 1755 - 1766
反应条件
triethylamine in tetrachloromethane
T=0°C; 0.166667 h;
参考文献
Kraegeloh, Konrad; Simchen, Gerhard
Synthesis, 1981 , # 1 p. 30 - 32
参考文献
Mizhiritskii, M. D.; Lebedev, E. P.; Fufaeva, A. N.
J. Gen. Chem. USSR (Engl. Transl.), 1982 , vol. 52, # 9 p. 2092 - 2094,1862 - 1864
反应条件
Li2S; triethylamine in acetonitrile
参考文献
Olah,G.A. et al.
Journal of Organic Chemistry, 1979 , vol. 44, p. 4272 - 4275
参考文献
Torkelson,S.; Ainsworth,C.
Synthesis, 1976 , p. 722 - 724
参考文献
Gostevskii, B. A.; Vyazankina, O. A.; Vyazankin, N. S.
J. Gen. Chem. USSR (Engl. Transl.), 1983 , vol. 53, # 8 p. 1843 - 1846,1659 - 1662
反应条件
in acetonitrile
2 h; Ambient temperature;
参考文献
Kraus, George A.; Wu, Yusheng
Anales de Quimica, 1995 , vol. 91, # 5-6 p. 394 - 398
