3-[(三甲基硅烷基)氧基]-2-环己烯-1-酮合成路线 （共 15 条）
反应条件
1.1: cesium fluoride / tetrahydrofuran / 0.17 h / 0 °C / Inert atmosphere
1.2: 18 h / 0 - 20 °C / Inert atmosphere
2.1: anhydrous butyl ether; toluene / 1 h / -78 - 100 °C / Inert atmosphere
View Scheme
参考文献
Batsomboon, Paratchata; Gold, Brian A.; Alabugin, Igor V.; Dudley, Gregory B.
Synthesis (Germany), 2012 , vol. 44, # 12 art. no. SS-2012-C0221-ST, p. 1818 - 1824
反应条件
1: 52 percent / ZnCl2 / CH2Cl2; diethyl ether / 1 h / 0 °C
2: 72 percent / NH2-NH2 / ethanol / 4 h / Ambient temperature
View Scheme
参考文献
Croce, Piero Dalla; Rosa, Concetta La
Synthesis, 1984 , # 11 p. 982 - 983
反应条件
1: 52 percent / ZnCl2 / CH2Cl2; diethyl ether / 1 h / 0 °C
2: 75 percent / ethanol / 4 h / Ambient temperature
View Scheme
参考文献
Croce, Piero Dalla; Rosa, Concetta La
Synthesis, 1984 , # 11 p. 982 - 983
反应条件
4 A molecular sieve; boron trifluoride diethyl etherate in dichloromethane
T=0°C; 48 h;
参考文献
Kurdyumov, Aleksey V.; Lin, Nan; Hsung, Richard P.; Gullickson, Glen C.; Cole, Kevin P.; Sydorenko, Nadiya; Swidorski, Jacob J.
Organic Letters, 2006 , vol. 8, # 2 p. 191 - 193
反应条件
in diethyl ether
20 h;
参考文献
Zhou, Yong Fan; Huang, Nai Zheng
Synthetic Communications, 1982 , vol. 12, # 10 p. 795 - 800
