lithium aluminium tetrahydride in neat (no solvent) byproducts: N2, ClCH2CO2CH2CH3, C6H5COCH2CO2C2H5; 1 equiv of diazoester adding to an equimolar mixt. of Ge deriv. and PhCHO to result in an exothermic reaction with N2 evolution; supentatant treating with LiAlH4 in ether; analyzed by gas chromy. and NMR spectroscopy;
参考文献
Castel, A.; Riviere, P.; Satge, J.
Journal of Organometallic Chemistry, 1982 , vol. 232, # 2 p. 137 - 146
in neat (no solvent) byproducts: N2, ClCH2CO2CH2CH3; 1 equiv of diazoester adding slowly to an equimolar mixt. of Ge and Sn deriv. to result in exothermic reaction with N2 evolution; after 4 h at 20°C concg., diene ligand adding, heating in a sealed tube for 12h at 120°C; analyzed by gas chromy. and NMR spectroscopy;
参考文献
Castel, A.; Riviere, P.; Satge, J.
Journal of Organometallic Chemistry, 1982 , vol. 232, # 2 p. 137 - 146
in neat (no solvent) byproducts: N2, ClCH2CO2CH2CH3; 1 equiv of diazoester adding slowly to an equimolar mixt. of Ge and Sn deriv. to result in exothermic reaction with N2 evolution; after 4 h at 20°C concg., diene ligand adding, heating in a sealed tube for 12h at 120°C; analyzed by gas chromy. and NMR spectroscopy;
参考文献
Castel, A.; Riviere, P.; Satge, J.
Journal of Organometallic Chemistry, 1982 , vol. 232, # 2 p. 137 - 146
in diethyl ether T=20°C; 8 h, then overnight; Yield given. Yields of byproduct given. Title compound not separated from byproducts;
参考文献
Mastryukova, T. A.; Uryupin, A. B.; Orlov, M.; Eremich, D.; Kabachnik, M. I.
J. Gen. Chem. USSR (Engl. Transl.), 1981 , vol. 51, # 7 p. 1475 - 1477,1251 - 1253
