hydrogen; 10percent Pd/C in methanol T=25°C; Hydrogenolysis; P=1551.49 Torr; 3 h;

1: N-Fmoc-Phe-Wang resin With piperidine in N,N-dimethyl-formamide Wang resin; 2: N-(9-fluorenylmethoxycarbonyl)glycine With O-(6-chloro-1H-benzotriazol-1-yl)-1,1,3,3-tetramethyluronium hexafluorophosphate; diisopropylamine; ethyl (hydroxylimino)cyanoacetate in N,N-dimethyl-formamide 0.75 h; Wang resin; 3: N-(9-fluorenylmethoxycarbonyl)glycine Further stages;

1: With sodium hydroxide; chymotrypsin T=37°C; 24 h; Enzymatic reaction; 2: With triflic acid-d1 T=20°C; 9 h; Enzymatic reaction;

β-D-glucosidase; nitrate buffer in water T=37°C; 6 h;

hydrogen; carboxypeptidase A; palladium on activated charcoal 1.) acetic acid-2-methoxyethanol; 2.) water, 25 deg C, 24 h;

ammonium cerium(IV) nitrate in various solvent(s) T=40 - 80°C; pH=7.0;

ammonium cerium(IV) nitrate in various solvent(s) T=40 - 80°C; pH=7.0;