2-甲-4-戊烯-2-醇合成路线 (共 65 条)
反应条件
1: HCl / 25 °C 2: AlCl3 View Scheme
参考文献
Colonge; Garnier
Bulletin de la Societe Chimique de France, 1948 , p. 436,438
反应条件
1: benzoyl peroxide 2: aq. KOH / ethanol View Scheme
参考文献
Surzur,J.-M.; Teissier,P.
Bulletin de la Societe Chimique de France, 1970 , p. 653 - 664
反应条件
pyridine; xanthone powder; bis(2,4-acetylacetonate)cobalt(II); hydrogen in tetrahydrofuran P=760 Torr; Ambient temperatureIrradiation; Yield given. Yields of byproduct given. Title compound not separated from byproducts;
参考文献
Chow, Yuan L.; Huang, Yu-Jin; Dragojlovic, Veljko
Canadian Journal of Chemistry, 1995 , vol. 73, # 5 p. 740 - 742
参考文献
Putochin
Chemische Berichte, 16 Ref. <1883>,2285
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Konnonowitz
Journal fuer Praktische Chemie (Leipzig), 1884 , vol. <2>30, p. 399
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Dijew
Journal fuer Praktische Chemie (Leipzig), 1883 , vol. <2>27, p. 364,377
反应条件
in neat (no solvent) byproducts: acetone, NaCl; addn. of Na to carbinol (room temp.), heating to 70°C (5 h), dropwise addn. of Bu2SnCl2 (as soln. in carbinol); distn. (reduced pressure);
参考文献
Tagliavini et al.
Inorganica Chimica Acta, 1978 , vol. 26, p. L41
反应条件
in neat (no solvent) byproducts: acetone, water; 20°C, 6 h (distn. off of ketone); distn. (reduced pressure);
参考文献
Tagliavini et al.
Inorganica Chimica Acta, 1978 , vol. 26, p. L41
反应条件
1: 62 percent / benzoyl peroxide, HBr / benzene / Ambient temperature 2: 30 percent / H2O2, silver tetrafluoroborate / diethyl ether / 0.5 h / -78 °C 3: silver tetrafluoroborate, thianthrene 5-oxide / CH2Cl2 / 0.5 h / var. silver salts, solvents, and oxygen trapping reagents; other hydroperoxides View Scheme
参考文献
Bloodworth, A. J.; Melvin, T.; Mitchell, John C.
Journal of Organic Chemistry, 1988 , vol. 53, # 5 p. 1078 - 1082
反应条件
permanganate(VII) ion
参考文献
Saizew,M.; Saizew,A.
Justus Liebigs Annalen der Chemie, 1877 , vol. 185, p. 161,168
参考文献
Schirokow
Journal fuer Praktische Chemie (Leipzig), 1881 , vol. <2>23, p. 201
参考文献
Saizew,M.; Saizew,A.
Justus Liebigs Annalen der Chemie, 1877 , vol. 185, p. 151,175