mono(bis(di-tert-butyl(4-(dimethylamino)phenyl)phosphonio)palladium(II))dichloride; caesium carbonate in water; toluene T=100°C; Suzuki-Miyaura Coupling; 14 h; Inert atmosphere;

[2,2']bipyridinyl; [NiCl2(py)4] in tetrahydrofuran T=20°C; Negishi coupling reaction; 12 h; Inert atmosphere;

1: copper(l) iodide; lithium methanolate / N,N-dimethyl-formamide / 24 h / 20 °C / |Glovebox 2: KHF2 / N,N-dimethyl-formamide; water / 0.5 h / 0 °C / |Glovebox 3: caesium carbonate; mono(bis(di-tert-butyl(4-(dimethylamino)phenyl)phosphonio)palladium(II))dichloride / water; toluene / 14 h / 100 °C / |Inert atmosphere View Scheme