1-苯甲酰基氮杂环庚-2-酮合成路线 （共 10 条）
反应条件
in tetrahydrofuran T=50°C; Title compound not separated from byproducts;
参考文献
Stehlicek, Jaroslav; Sebenda, Jan
Collection of Czechoslovak Chemical Communications, 1980 , vol. 45, # 9 p. 2524 - 2531
反应条件
1: epsilon-caprolactam With n-butyllithium in tetrahydrofuran; hexane
T=-78°C; 0.5 h;
2: benzyl chloroformate in tetrahydrofuran; hexane
T=-78 - 20°C; 2 h;
参考文献
Gigant, Nicolas; Gillaizeau, Isabelle
Organic Letters, 2012 , vol. 14, # 17 p. 4622 - 4625
参考文献
Clariant GmbH
Patent: US6028192 A1, 2000 ;
反应条件
N,N-dimethyl-formamide
参考文献
Hall et al.
Journal of the American Chemical Society, 1958 , vol. 80, p. 6420,6421
反应条件
1: With copper(I) bromide in tetrachloromethane; acetonitrile
T=20°C; 0.25 h; Inert atmosphere;
2: With N-bromosuccinmide in tetrachloromethane; acetonitrile
T=75°C; 28 h; Inert atmosphere;
参考文献
Wang, Long; Fu, Hua; Jiang, Yuyang; Zhao, Yufen
Chemistry - A European Journal, 2008 , vol. 14, # 34 p. 10722 - 10726
反应条件
sodium periodate; RuO4 in tetrachloromethane; water
72 h; Ambient temperature; Yield given;
参考文献
Tangari, Nicola; Giovine, Maria; Morlacchi, Flaviano; Vetuschi, Claudio
Gazzetta Chimica Italiana, 1985 , vol. 115, # 6 p. 325 - 328
反应条件
1: 67 percent / KOH / dimethylsulfoxide / 0.5 h
2: 68 percent / xylene / 2 h / 150 °C
View Scheme
参考文献
MaGee, David I.; Ramaseshan, Mahesh; Leach, James D.
Canadian Journal of Chemistry, 1995 , vol. 73, # 12 p. 2111 - 2118
反应条件
1: 67 percent / KOH / dimethylsulfoxide / 0.5 h
2: 68 percent / xylene / 2 h / 150 °C
View Scheme
参考文献
MaGee, David I.; Ramaseshan, Mahesh; Leach, James D.
Canadian Journal of Chemistry, 1995 , vol. 73, # 12 p. 2111 - 2118
参考文献
Ruzicka
Helvetica Chimica Acta, 1921 , vol. 4, p. 491
反应条件
in tetrahydrofuran
T=50°C; Title compound not separated from byproducts;
参考文献
Stehlicek, Jaroslav; Sebenda, Jan
Collection of Czechoslovak Chemical Communications, 1980 , vol. 45, # 9 p. 2524 - 2531
