反应条件
1: 80 percent / Br2 / acetone; H2O / 3 h / -20 - 20 °C 2: 1.) BH3*SMe2, (R)-B-methyl-4,5,5-triphenyl-1,3,2-oxazaborolidine, 2.) (-)-diethyl tartrate, titanium(IV) isopropoxide, t-BuOOH / 1.) THF, 0 deg C, 2.) CH2Cl2, isooctane, -20 deg C, 2 d 3: 81 percent / H2 / Pd/C / ethanol / 2 h / 38000 Torr View Scheme
参考文献
Bach, Jordi; Berenguer, Ramon; Garcia, Jordi; Lopez, Marta; Manzanal, Judith; Vilarrasa, Jaume
Tetrahedron, 1998 , vol. 54, # 49 p. 14947 - 14962
