(R)-4-溴氧化苯乙烯合成路线 （共 11 条）
反应条件
tri-n-butylmethylammonium chloride; sodium hydroxide in 2-methyl tetrahydrofuran; water T=20°C;
参考文献
US2010/216812 A1, ;
Page/Page column 53 ;
US 20100216812 A1
反应条件
(S,S)-salen-CoIII-OAc; water in tetrahydrofuran T=0 - 20°C; optical yield given as percent ee;
参考文献
Cattoen, Xavier; Pericas, Miquel A.
Tetrahedron, 2009 , vol. 65, # 39 p. 8199 - 8205
反应条件
1: With sodium hydride in tetrahydrofuran T=0 - 20°C; 2.08333 h; 2: With methanol in tetrahydrofuran T=0°C;
参考文献
WO2007/57687 A1, ;
Page/Page column 26-27 ;
WO 2007/057687 A1
反应条件
iodosylbenzene; homochiral chloroiron(III) porphyrin in benzene T=25°C; 3 h; other reagents, solvents, temperatures, reaction times; Product distribution;
参考文献
Journal of Organic Chemistry, , vol. 62, # 16 p. 5514 - 5521
反应条件
D-glucose T=30°C; 5 h; Enzymatic reaction; Reagent/catalystTime; enantioselective reaction;
参考文献
Li, Aitao; Liu, Ji; Pham, Son Q.; Li, Zhi
Chemical Communications, 2013 , vol. 49, # 98 p. 11572 - 11574
反应条件
1.1: dimethylsulfide borane complex; (R)-tetrahydro-1-methyl-3,3-diphenyl-1H,3H-pyrrolo[1,2-c]-[1,3,2]oxazaborole / toluene; 2-methyl tetrahydrofuran / 4 h / 40 - 45 °C 1.2: 1 h / 10 °C 2.1: sodium hydroxide; tri-n-butylmethylammonium chloride / water; 2-methyl tetrahydrofuran / 2.33 h / 20 °C View Scheme
反应条件
water in ethanol T=27°C; 2 h; biohydrolysis using Beauveria sulfurescens; pH 8; Yield given. Yields of byproduct given. Title compound not separated from byproducts;
参考文献
Journal of Organic Chemistry, , vol. 61, # 21 p. 7402 - 7407
反应条件
sodium hydroxide in tetrahydrofuran T=25°C; Title compound not separated from byproducts;
参考文献
Tetrahedron Letters, , vol. 47, # 3 p. 349 - 351
反应条件
1: pyridine 2: NaOH / methanol / 2 h / 20 °C View Scheme
参考文献
Chemical Research in Toxicology, , vol. 11, # 1 p. 44 - 53
反应条件
sodium hydride in dimethyl sulfoxide T=20°C;
参考文献
Phosphorus, Sulfur and Silicon and the Related Elements, , vol. 186, # 5 p. 1274 - 1277
