反应条件
LiDBB in tetrahydrofuran; diethyl ether
Ar-atmosphere; addn. of LiDBB (THF, 7 equivs.) to Et2O soln. of tribromobenzene at -75°C, warming to -40°C within 5 min, addn. of excess Me3SnCl, stirring for 15 min, addn of MeOD, warming to room temp.; addn. of hexamethylbenzene, extn. (H2O:Et2O), sepn. of org. layer, washing (H2O, brine), drying (MgSO4), filtration, evapn.; GC/MS;
参考文献
Rot, Nicolette; Bickelhaupt, Friedrich
Organometallics, 1997 , vol. 16, # 23 p. 5027 - 5031
