1: triallyl(4-methoxyphenyl)silane With tetrabutyl ammonium fluoride in tetrahydrofuran; water
T=20°C; 1 h;
2: 3-chloro-pyridine With 2-(dicyclohexylphosphino)-2',4',6'-tri-i-propyl-1,1’-biphenyl; bis(η3-allyl-μ-chloropalladium(II)) in tetrahydrofuran; water
T=80°C; 6 h;
(N,N'-diarylimidazol-2-ylidene)-based palladacycle; sodium t-butanolate in 1,4-dioxane
T=70°C; 2 h;
参考文献
Viciu, Mihai S.; Kelly III, Roy A.; Stevens, Edwin D.; Naud, Frederic; Studer, Martin; Nolan, Steven P.
Organic Letters, 2003 , vol. 5, # 9 p. 1479 - 1482
potassium phosphate; tris-(dibenzylideneacetone)dipalladium(0) in tert-butyl alcohol
T=110°C; 24 h;
参考文献
Ikawa, Takashi; Barder, Timothy E.; Biscoe, Mark R.; Buchwald, Stephen L.
Journal of the American Chemical Society, 2007 , vol. 129, # 43 p. 13001 - 13007