1: With piperidine in N,N-dimethyl-formamide 2 h; Reflux; 2: With sodium periodate in water; N,N-dimethyl-formamide T=20°C; 1 h;

暂无反应条件数据

pyridona in various solvent(s) T=160°C; 4 h;

1.1: trichlorophosphate / chloroform / 1 h / Reflux 1.2: 20 °C / pH 8 2.1: piperidine / N,N-dimethyl-formamide / 2 h / Reflux 2.2: 1 h / 20 °C View Scheme

1.1: acetic acid / 1.5 h / Reflux 2.1: trichlorophosphate / chloroform / 1 h / Reflux 2.2: 20 °C / pH 8 3.1: piperidine / N,N-dimethyl-formamide / 2 h / Reflux 3.2: 1 h / 20 °C View Scheme

perchloric acid; ammonium cerium(IV) nitrate in water; acetic acid T=35 - 50°C; study of the kinetics of the oxidation reaction of the methyl group of various bicyclic derivatives by Ce(IV); activation parameters, Δ(excit.) are given; Product distributionKineticsThermodynamic data;