4A,5,8,8a-四氢-[1,4]萘醌合成路线 （共 15 条）
反应条件
1: 91 percent / AcOH; aq. HBr / 0.25 h / 110 - 115 °C
2: 98 percent / H2SO4 / 0.25 h / 20 °C
View Scheme
参考文献
Tririya, Gasirat; Zanger, Murray
Synthetic Communications, 2004 , vol. 34, # 17 p. 3047 - 3059
反应条件
1: 91 percent / AcOH; aq. HBr / 0.25 h / 110 - 115 °C
2: 98 percent / H2SO4 / 0.25 h / 20 °C
3: 97 percent / m-CPBA / CH2Cl2 / 12 h / 20 °C
View Scheme
参考文献
Tririya, Gasirat; Zanger, Murray
Synthetic Communications, 2004 , vol. 34, # 17 p. 3047 - 3059
反应条件
1: 91 percent / AcOH; aq. HBr / 0.25 h / 110 - 115 °C
2: 68 percent / NaOH / H2O / 12 h / 20 °C
3: 91 percent / m-CPBA / CH2Cl2 / 12 h / 20 °C
4: 42 percent / MgBr2*Et2O / toluene / 6 h / Heating
5: 54 percent / AlCl3; NaCl / 180 °C
View Scheme
参考文献
Tririya, Gasirat; Zanger, Murray
Synthetic Communications, 2004 , vol. 34, # 17 p. 3047 - 3059
参考文献
Hiramatsu, Mitsuo; Fujinami, Tatsuo; Sakai, Shizuyoshi
Journal of Organometallic Chemistry, 1981 , vol. 218, # 3 p. 409 - 416
反应条件
in chlorobenzene
T=200°C; 15 h;
参考文献
Tamura, Y.; Wada, A.; Sasho, M.; Kita, Y.
Tetrahedron Letters, 1981 , vol. 22, # 43 p. 4283 - 4286
