2-(2-甲氧基苯基)环氧乙烷合成路线 （共 13 条）
反应条件
sodium tetrahydroborate in benzene T=45°C; 2.5 h;
参考文献
Shaozu, Wu; Yulan, Zhang; Huidong, Wang
Gazzetta Chimica Italiana, 1991 , vol. 121, # 11 p. 519 - 520
反应条件
lithium aluminium tetrahydride in tetrahydrofuran 3.5 h; 0 deg C to roomtemp; Yield given;
参考文献
Kayser, Margaret M.; Morand, Peter
Canadian Journal of Chemistry, 1980 , vol. 58, # 3 p. 302 - 306
反应条件
sodium hydrogencarbonate; 3-chloro-benzenecarboperoxoic acid in dichloromethane; water
T=20°C; 2.5 h;
参考文献
Bernasconi, Silvana; Orsini, Fulvia; Sello, Guido; Di Gennaro, Patrizia
Tetrahedron Asymmetry, 2004 , vol. 15, # 10 p. 1603 - 1606
反应条件
1: Me3SOI With sodium hydride; ammonium chloride in dimethyl sulfoxide
T=40°C; 1 h;
2: ortho-anisaldehyde in dimethyl sulfoxide
T=15 - 20°C; 1 h;
参考文献
Nimbus Apollo, Inc.; Harriman, Geraldine C.; Masse, Craig E.; Harwood, James; Bhat, Sathesh; Greenwood, Jeremy Robert
Patent: US2013/123231 A1, 2013 ;
Location in patent: Paragraph 0704; 0705; 0706 ;
反应条件
sodium hydroxide; tetra-(n-butyl)ammonium iodide in dichloromethane
120 h; Ambient temperature;
参考文献
Williams, Robert M.; Glinka, Tomasz; Gallegos, Renee; Ehrlich, Paul P.; Flanagan, Mark E.; Coffman, Hazel; Park, Gyoosoon
Tetrahedron, 1991 , vol. 47, # 14-15 p. 2629 - 2642
反应条件
sodium hydride in dimethyl sulfoxide
参考文献
Guy; Doussot; Ferroud; Garreau; Godefroy-Falguieres
Synthesis, 1992 , # 9 p. 821 - 822
反应条件
trimethyl-sulfonium iodide; potassium hydroxide in dimethyl sulfoxide
T=80°C; 1 h;
参考文献
Penkett, Clive S.; Woolford, Jason A.; Read, Timothy W.; Kahan, Rachel J.
Journal of Organic Chemistry, 2011 , vol. 76, # 5 p. 1295 - 1304
反应条件
potassium hydroxide in 1,4-dioxane; water
参考文献
Tanabe Seiyaku Co., Ltd.
Patent: US4131686 A1, 1978 ;
反应条件
iodosylbenzene; Fe-Cl(S)-eclipsed in dichloromethane
T=0°C; 2.5 h; Yield given. Yields of byproduct given;
参考文献
Naruta, Yoshinori; Tani, Fumito; Maruyama, Kazuhiro
Chemistry Letters, 1989 , p. 1269 - 1272
反应条件
1: With tetramethylene sulfide; N,N,N',N'-tetra-methylnaphthalene-1,8-diamine in dichloromethane
T=20°C; 0.416667 h; Inert atmosphere;
2: With 1-tert-butyl-2,2,4,4,4-pentakis(dimethylamino)-25,45-catenodi(phosphazene) in tetrahydrofuran; dichloromethane
T=20°C; Inert atmosphere;
参考文献
Piccinini, Alessandro; Kavanagh, Sarah A.; Connon, Paul B.; Connon, Stephen J.
Organic Letters, 2010 , vol. 12, # 3 p. 608 - 611
