N-甲基-N-苯基丙烯酰胺合成路线 （共 11 条）
反应条件
Grubb's 2nd generation catalyst in dichloromethane T=40°C; 15 h;
参考文献
Choi, Tae-Lim; Chatterjee, Arnab K.; Grubbs, Robert H.
Angewandte Chemie - International Edition, 2001 , vol. 40, # 7 p. 1277 - 1279
反应条件
potassium phosphate; Pd((CH3)2C6H3NC(CH3)CHC(CH3)NC6H3(CH3)2)(CH3)(P(CH2CH3)3); tetrabutylammomium bromide in water; N,N-dimethyl-formamide T=85°C; Heck coupling; 10 h; optical yield given as percent destereoselective reaction;
参考文献
Lee, Dong-Hwan; Taher, Abu; Hossain, Shahin; Jin, Myung-Jong
Organic Letters, 2011 , vol. 13, # 20 p. 5540 - 5543
参考文献
Moureu
Bulletin de la Societe Chimique de France, 1893 , vol. <3>9, p. 423
Annales de Chimie (Cachan, France), 1894 , vol. <7>2, p. 185
反应条件
samarium diiodide in THF-d8 (tetrahydrofuran-d8)
T=-78°C; Baylis-Hillman reaction; 0.0833333 h;
参考文献
Youn; Park; Kim
Chemical Communications, 2000 , # 20 p. 2005 - 2006
反应条件
1: N1-Phenylacrylamide With sodium hydride in diethyl ether
T=0 - 20°C;
2: methyl iodide in diethyl ether
T=0 - 20°C;
参考文献
Wu, Tao; Mu, Xin; Liu, Guosheng
Angewandte Chemie - International Edition, 2011 , vol. 50, # 52 p. 12578 - 12581
反应条件
samarium diiodide; methanol-d4 in tetrahydrofuran
T=-78°C; Baylis-Hillman reaction; Title compound not separated from byproducts.;
参考文献
Youn; Park; Kim
Chemical Communications, 2000 , # 20 p. 2005 - 2006
反应条件
1.1: dichloromethane / 0 - 20 °C
2.1: sodium hydride / diethyl ether / 0 - 20 °C
2.2: 0 - 20 °C
View Scheme
参考文献
Wu, Tao; Mu, Xin; Liu, Guosheng
Angewandte Chemie - International Edition, 2011 , vol. 50, # 52 p. 12578 - 12581
反应条件
1: acetone
2: bei der Destillation unter gewoehnlichem Druck
View Scheme
参考文献
Mayer; van Zuetphen; Philipps
Chemische Berichte, 1927 , vol. 60, p. 861
反应条件
tetracarbonylnickel(0); acrylic acid
参考文献
Rohm and Haas Co.
Patent: US2773063 , 1954 ;
反应条件
diisobutylaluminium hydride; cobalt(II) 2,4-pentanedionate in tetrahydrofuran; hexane
T=0°C; 4 h;
参考文献
Ikeno, Taketo; Kimura, Tomomi; Ohtsuka, Yuhki; Yamada, Tohru
Synlett, 1999 , # 1 p. 96 - 98
