in diethyl ether
1.) -60 to -50 deg C, 15 min, 2.) -30 deg C, 5-6 h;
参考文献
Kuramshin, E. M.; Kulak, L. G.; Zlot-skii, S. S.; Rakhmankulov, D. L.
Journal of Organic Chemistry USSR (English Translation), 1986 , vol. 22, # 9 p. 1783 - 1786
Zhurnal Organicheskoi Khimii, 1986 , vol. 22, # 9 p. 1986 - 1989
Zorin, V. V.; Zelechonok, Yu. B.; Zlotskii, S. S.; Rakhmankulov, D. L.
Chemistry of Heterocyclic Compounds (New York, NY, United States), 1984 , vol. 20, # 1 p. 20 - 23
Khimiya Geterotsiklicheskikh Soedinenii, 1984 , vol. 20, # 1 p. 25 - 28
tertiary butyl peroxybenzenoate
T=100 - 130°C; 4 h; further products (2-hydroxymethoxymethyl-1,3-dioxolane and CH2O homologues) isolated; also reaction with paraformaldehyde, and other initiators investigated; Product distributionMechanism;
参考文献
Sanderson, John R.; Yeakey, Ernest L.; Lin, Jiang J.; Duranleau, Roger; Marquis, Edward T.
Journal of Organic Chemistry, 1987 , vol. 52, # 15 p. 3243 - 3246
Kuramshin, E. M.; Kulak, L. G.; Zlot-skii, S. S.; Rakhmankulov, D. L.
Journal of Organic Chemistry USSR (English Translation), 1986 , vol. 22, # 9 p. 1783 - 1786
Zhurnal Organicheskoi Khimii, 1986 , vol. 22, # 9 p. 1986 - 1989
oxygen
T=70°C; 16.5 h; other substituted 1,3-dioxolanes; rate of consumption of oxygen, relative rate of formation of glycol; Product distributionMechanism;
参考文献
Schnurpfeil, D.; Teubner, M.
Journal fuer Praktische Chemie/Chemiker-Zeitung, 1994 , vol. 336, # 2 p. 155 - 159
Kuramshin, E. M.; Kulak, L. G.; Zlot-skii, S. S.; Rakhmankulov, D. L.
Journal of Organic Chemistry USSR (English Translation), 1986 , vol. 22, # 9 p. 1783 - 1786
Zhurnal Organicheskoi Khimii, 1986 , vol. 22, # 9 p. 1986 - 1989
