反应条件
1: tert-butyl(dimethyl){[(4E)-5-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)pent-4-enyl]oxy}silane With 1,1-dimethylethylmagnesium chloride in tetrahydrofuran T=-78 - 0°C; Suzuki-Miyaura coupling; 1 h; 2: c-heptyl-Cl With [FeCl2(3,5-tBu2-SciOPP)]; magnesium bromide in tetrahydrofuran; N-undecane T=-78 - 40°C; Suzuki-Miyaura coupling; 24 h; stereospecific reaction;
参考文献
Hashimoto, Toru; Hatakeyama, Takuji; Nakamura, Masaharu
Journal of Organic Chemistry, 2012 , vol. 77, # 2 p. 1168 - 1173
