potassium cyanide in diethyl ether Refluxing in ether for 1 h, evapn. of ether in vac., treating of residue with aq. KCN.; Extg. with CHCl3, NMR, MS. Further products.;
1,1-dimethylpropan-1-ol; lithium bromide in diethyl ether T=18°C; product distribution as a function of <tert-amyl alcohol>0/<TMPO(1.)>0; Product distributionMechanismKinetics;
参考文献
Journal of the American Chemical Society, , vol. 111, # 14 p. 5405 - 5412