反应条件
1: 1.) triethylammonium chloride, copper(II) chloride; 2.) triethylamine / 1.) acetonitrile, reflux, 35 h; 2.) acetonitrile, CH2Cl2, reflux, 60 min 2: 60 percent / 2.2 M NaOH, 30percent H2O2 / H2O; acetone / 1.) 40 deg C, 60 min; 2.) 50 deg C, 90 min 3: 1.) n-butyllithium / 1.) THF, ethyl ether, hexane, -95 deg C, 60 min; 2.) THF, ethyl ether, hexane, (-95 deg C) - room temperature 4: i-Bu2AlH / hexane View Scheme
参考文献
Journal of Organometallic Chemistry, , vol. 341, p. 293 - 314
