bis(1,5-cyclooctadiene)nickel (0); 1,8-diazabicyclo[5.4.0]undec-7-ene in tetrahydrofuran T=0°C; P=760 Torr; 2 h; Yield givenYields of byproduct given. Title compound not separated from byproducts;
1.1: n-butyllithium / tetrahydrofuran; hexane / -78 °C / |Inert atmosphere 1.2: 2 h / -78 - 20 °C / |Inert atmosphere 2.1: tetrabutyl ammonium fluoride / tetrahydrofuran / 20 °C / |Inert atmosphere 3.1: AuBr3; sodium chloride / water / 0.5 h / 20 °C / |Darkness; |Sealed tube View Scheme
参考文献
Minkler, Stefan R. K.; Isley, Nicholas A.; Lippincott, Daniel J.; Krause, Norbert; Lipshutz, Bruce H.
Organic Letters, 2014 , vol. 16, # 3 p. 724 - 726
N,N,N',N',N'',N''-hexamethylphosphoric triamide; 2-(dimethylamino)-ethanol; samarium diiodide Ambient temperature; Yields of byproduct given. Title compound not separated from byproducts;
