反应条件
1: 48 percent / iron (III) sulphate on silica gel / hexane / 1.42 h / 45 °C
2: 84 percent / pyridine / CH2Cl2 / 16 h / Ambient temperature
3: 46 percent / I2, 1,2-bis(diphenylphosphino)ethane / CH2Cl2 / 4 h / Ambient temperature
4: 34 percent / dimethylsulfoxide / 2 h / Ambient temperature
5: 79 percent / trifluoroacetic acid, H2O / CH2Cl2
6: 1.) n-BuLi, 2.) HMPA / 1.) THF, hexane, 0 deg C, 10 min, 2.) THF, hexane, 0 deg C, 1.5 h
7: 88 percent / H2 / 10percent Pd/C / diethyl ether / 16 h
8: 44 percent / molecular sieves 4 A, pyridinum dichromate / dimethylformamide / 120 h / Ambient temperature
9: 94 percent / 10percent aq. tetrabutylammonium hydroxide / CH2Cl2 / 16 h
View Scheme
参考文献
Wallace, Paul A.; Minnikin, David E.; McCrudden, Katharine; Pizzarello, Andrea
Chemistry and Physics of Lipids, 1994 , vol. 71, # 2 p. 145 - 162
