2,5-双(氯甲基)-对-二甲苯合成路线 （共 14 条）
反应条件
1: glacial acetic acid 2: alkaline solution 3: concentrated aqueous HBr / 100 °C View Scheme
参考文献
v. Braun; Nelles
Chemische Berichte, 1934 , vol. 67, p. 1094,1096
反应条件
1: glacial acetic acid 2: alkaline solution View Scheme
参考文献
v. Braun; Nelles
Chemische Berichte, 1934 , vol. 67, p. 1094,1096
反应条件
1: aq. HNO3, H2SO4 / CHCl3 / 5 h / Ambient temperature 2: HNO3, O2 / Heating 3: diethyl ether; methanol 4: Zn, aq. AcOH 5: aq. NaOH / ethanol / Heating 6: 180 - 200 °C View Scheme
参考文献
Hopff,H. et al.
Helvetica Chimica Acta, 1961 , vol. 44, p. 367 - 379
反应条件
1-(n-hexyl)-3-methylimidazolium triflate; 1,4-diaza-bicyclo[2.2.2]octane; copper (II) 2-ethylhexanoate; bis(acetylacetonate)oxovanadium; oxygen T=120°C; P=760.051 Torr; 24 h;
参考文献
Arkivoc, , vol. 2010, # 9 p. 63 - 74
反应条件
1: dimethylsulfoxide 2: (i) NaOMe, (ii) /BRN= 969190/ 3: (i) aq. KOH, (ii) aq. HCl, (iii) aq. Br2 View Scheme
参考文献
Wheland,R.S.; Martin,E.L.
Journal of Organic Chemistry, 1975 , vol. 40, # 21 p. 3101 - 3109
反应条件
hydrogenchloride in water; 2-methyl cyclohexane
T=60°C; 8 h;
参考文献
Hu; Liu; Lu; Ge; Zhang
Journal of the Iranian Chemical Society, 2011 , vol. 8, # 1 p. 131 - 141
反应条件
hydrogenchloride; [emim][PF6]
T=70°C; 5 h; Ionic liquid;
参考文献
Wang, Yun; Xi, Yanli
Journal of the Chilean Chemical Society, 2013 , vol. 58, # 4 p. 2196 - 2199
参考文献
v. Braun; Nelles
Chemische Berichte, 1934 , vol. 67, p. 1094,1096
Full Text Show Details
Akin; Stamatoff; Bogert
Journal of the American Chemical Society, 1937 , vol. 59, p. 1268,1271
反应条件
hydrogenchloride; zinc(II) chloride in acetic acid
T=80 - 90°C; 24 h;
参考文献
Cagniant,P. et al.
Bulletin de la Societe Chimique de France, 1961 , p. 2225 - 2235
反应条件
sodium t-butanolate in methanol
Substitution; 0.75 h;
参考文献
van der Borght, Michael; Vanderzande, Dirk; Adriaensens, Peter; Gelan, Jan
Journal of Organic Chemistry, 2000 , vol. 65, # 2 p. 284 - 289
