[二(甲硫基)甲基]膦酸二乙酯合成路线 （共 14 条）
反应条件
1: 85 percent / n-Bu3SnH, AIBN / toluene / 1 h / Heating 2: 55 percent / n-Bu3SnH, AIBN / toluene / 1 h / Heating View Scheme
参考文献
Balczewski,Piotr
Phosphorus, Sulfur and Silicon and the Related Elements, 1995 , vol. 104, # 14 p. 113 - 122
反应条件
1: 85 percent / n-Bu3SnH, AIBN / toluene / 1 h / Heating 2: n-BuLi / 1.) THF, -78 deg C, 2.) THF, from -78 to 25 deg C 3: 81 percent / n-Bu3SnH, AIBN / toluene / 1 h / Heating View Scheme
参考文献
Balczewski,Piotr
Phosphorus, Sulfur and Silicon and the Related Elements, 1995 , vol. 104, # 14 p. 113 - 122
反应条件
2,2'-azo-bisisobutyronitrile; tri-n-butyl-tin hydride in toluene 1 h; Heating;
参考文献
Balczewski,Piotr
Phosphorus, Sulfur and Silicon and the Related Elements, 1995 , vol. 104, # 14 p. 113 - 122
反应条件
n-butyllithium; oxygen in tetrahydrofuran T=-78°C; 1) 10 min, 2) 15 min;
参考文献
Mikolajczyk, Marian; Midura, Wanda; Grzejszczak, Slawomir
Tetrahedron Letters, 1984 , vol. 25, # 23 p. 2489 - 2492
反应条件
hydrogenchloride; methanethiol in acetic acid
参考文献
Gross, Hans; Keitel, Iris; Costisella, Burkhard; Mikolajczyk, Marian; Midura, Wanda
Phosphorus and Sulfur and the Related Elements, 1983 , vol. 16, p. 257 - 262
反应条件
n-butyllithium in tetrahydrofuran; hexane
T=-78°C; sulphenylation of the metallated phosphonates monitored by low temp. 31P-NMR; Mechanism;
参考文献
Mikolajczyk, Marian; Balczewski, Piotr; Grzejszczak, Slawomir
Synthesis, 1980 , # 2 p. 127 - 129
反应条件
1: 1.) n-BuLi / 1.) hexane, THF, -78 deg C, 2.) -78 deg C
2: 1.) n-BuLi / 1.) Et2O, THF, -78 deg C, 10 min, 2.) room temp., 1 h; reflux, 30 min
View Scheme
参考文献
Mikolajczyk, Marian; Balczewski, Piotr
Synthesis, 1989 , # 2 p. 101 - 106
反应条件
1: 1.) n-BuLi / 1.) hexane, THF, -78 deg C, 2.) -78 deg C
2: 1.) n-BuLi / 1.) Et2O, THF, -78 deg C, 10 min, 2.) room temp., 1 h; reflux, 30 min
View Scheme
参考文献
Mikolajczyk, Marian; Balczewski, Piotr
Synthesis, 1989 , # 2 p. 101 - 106
反应条件
oxonium in tetrahydrofuran
T=-78°C;
参考文献
Bulpin, Andrew; Masson, Serge; Sene, Aboubacary
Tetrahedron Letters, 1989 , vol. 30, # 26 p. 3415 - 3418
反应条件
n-butyllithium
1.) Et2O, THF, -78 deg C, 10 min, 2.) room temp., 1 h; reflux, 30 min; Yield given. Multistep reaction;
参考文献
Mikolajczyk, Marian; Balczewski, Piotr
Synthesis, 1989 , # 2 p. 101 - 106
