hydrogen; 3-(cyclohexylamino)-4-isopropoxy-cyclobutenedione; palladium on activated charcoal in methanol T=20°C; Catalytic hydrogenation; Hydrogenolysis; 5 h; Title compound not separated from byproducts;
potassium hydroxide; potassium phosphate buffer; porcine kidney acylase I T=40°C; relative initial rate of hydrolysis, also with Aspergillus acylase I as a catalyst; with or without CoCl2;
参考文献
Journal of the American Chemical Society, , vol. 111, # 16 p. 6354 - 6364
hydrogen; lt;Rh((R)-cycphos)(NBD)gt;PF6 in ethyl acetate T=25°C; P=38000 Torr; effects of catalysts, pressure, temperature and solvents dependence of the optical yields, effect of added of NEt3;
参考文献
Journal of Organic Chemistry, , vol. 45, # 25 p. 5187 - 5193
hydrogen; lt;Rh((R)-cycphos)(NBD)gt;PF6 in tetrahydrofuran T=25°C; P=760 Torr; effects of catalysts, and solvents dependence of the optical yields, effect of added of NEt3;
参考文献
Journal of Organic Chemistry, , vol. 45, # 25 p. 5187 - 5193
