(4-[(三甲基甲硅烷基)乙炔]苯基)硼酸合成路线 （共 7 条）
反应条件
in diethyl ether T=20°C; 24 h;
参考文献
Iida, Hiroki; Shimoyama, Munenori; Furusho, Yoshio; Yashima, Eiji
Journal of Organic Chemistry, 2010 , vol. 75, # 2 p. 417 - 423
反应条件
copper(l) iodide; diethylamine; triphenylphosphine; bis-triphenylphosphine-palladium(II) chloride in N,N-dimethyl-formamide
T=120°C; Sonogashira reacion; 0.416667 h; microwave irradiation;
参考文献
Zheng, Shi-Long; Reid, Suazette; Lin, Na; Wang, Binghe
Tetrahedron Letters, 2006 , vol. 47, # 14 p. 2331 - 2335
反应条件
1: With n-butyllithium in diethyl ether
T=-78°C; 0.5 h;
2: With boric acid trimethyl ester in diethyl ether
T=-78 - 25°C; 14.5 h; Further stages.;
参考文献
Thoresen, Lars H.; Jiao, Guan-Sheng; Haaland, Wade C.; Metzker, Michael L.; Burgess, Kevin
Chemistry - A European Journal, 2003 , vol. 9, # 19 p. 4603 - 4610
反应条件
1: With n-butyllithium in tetrahydrofuran; hexane
T=-78°C; 0.25 h;
2: With boric acid trimethyl ester in tetrahydrofuran
T=25°C; 0.5 h;
参考文献
Wan, Chi-Wai; Burghart, Armin; Chen, Jiong; Bergstroem, Fredrik; Johansson, Lennart B.-A.; Wolford, Matthew F.; Kim, Taeg Gyum; Topp, Michael R.; Hochstrasser, Robin M.; Burgess, Kevin
Chemistry - A European Journal, 2003 , vol. 9, # 18 p. 4430 - 4441
反应条件
1: 100 percent / toluene / 1 h / Heating
2: 1.5 percent / triphenylphosphine; diethylamine; CuI / PdCl2(PPh3)2 / dimethylformamide / 0.42 h / 120 °C / microwave irradiation
View Scheme
参考文献
Zheng, Shi-Long; Reid, Suazette; Lin, Na; Wang, Binghe
Tetrahedron Letters, 2006 , vol. 47, # 14 p. 2331 - 2335
反应条件
in N,N-dimethyl-formamide
T=20°C; 0.25 h;
参考文献
Erb, William; Hellal, Akila; Albini, Mathieu; Rouden, Jacques; Blanchet, Jerome
Chemistry - A European Journal, 2014 , vol. 20, # 22 p. 6608 - 6612
反应条件
1.1: ethanol; water / 0.03 h / 20 °C
1.2: 1.25 h / 0 - 20 °C
2.1: N,N-dimethyl-formamide / 0.25 h / 20 °C
View Scheme
参考文献
Erb, William; Hellal, Akila; Albini, Mathieu; Rouden, Jacques; Blanchet, Jerome
Chemistry - A European Journal, 2014 , vol. 20, # 22 p. 6608 - 6612
