1-(4-氯苯基)1,3-丁二酮合成路线 （共 27 条）
反应条件
sodium ethanolate in ethanol Reflux;
参考文献
Gautam, Vertika; Chawla, Viney; Sonar, Pankaj K.; Saraf, Shailendra K.
E-Journal of Chemistry, 2010 , vol. 7, # 4 p. 1190 - 1195
反应条件
1: With sodium hydride in tetrahydrofuran T=0°C; 3 h; Heating / reflux; 2: With hydrogenchloride; water in tetrahydrofuran pH=5;
参考文献
US7297710 B1, ;
Page/Page column 18 ;
US 7297710 B1
反应条件
tetrachlorosilane; zinc(II) chloride in dichloromethane T=25°C; 5 h;
参考文献
Elmorsy, Saad S.; Badawy, Doria S.; Khatab, Tamer K.
Phosphorus, Sulfur and Silicon and the Related Elements, 2005 , vol. 180, # 1 p. 109 - 116
反应条件
L-proline T=20°C; 10 h;
参考文献
Shen, Zongxuan; Li, Bin; Wang, Lu; Zhang, Yawen
Tetrahedron Letters, 2005 , vol. 46, # 50 p. 8785 - 8788
反应条件
methanol; water; oxygen; toluene-4-sulfonic acid; palladium dichloride in N,N-dimethyl acetamide T=80°C; P=4560.31 Torr; 10 h; Autoclave; regioselective reaction;
参考文献
Mitsudome, Takato; Yoshida, Syuhei; Mizugaki, Tomoo; Jitsukawa, Koichiro; Kaneda, Kiyotomi
Angewandte Chemie - International Edition, 2013 , vol. 52, # 23 p. 5961 - 5964
Angew. Chem., 2013 , vol. 125, # 23 p. 6077 - 6080,4
反应条件
[Pd(η3-1-Ph-allyl)(μ-Cl)]2; cataCXium®A; caesium carbonate T=60°C; P=2250.23 Torr; 36 h; GloveboxInert atmosphereAutoclave;
参考文献
Schranck, Johannes; Tlili, Anis; Alsabeh, Pamela G.; Neumann, Helfried; Stradiotto, Mark; Beller, Matthias
Chemistry - A European Journal, 2013 , vol. 19, # 38 p. 12624 - 12628
反应条件
hydrogenchloride in water T=80°C; 1 h;
参考文献
Korsager, Signe; Nielsen, Dennis U.; Taaning, Rolf H.; Lindhardt, Anders T.; Skrydstrup, Troels
Chemistry - A European Journal, 2013 , vol. 19, # 52 p. 17687 - 17691
反应条件
aluminium trichloride T=45 - 55°C; anschliessend Erwaermen auf 60-70grad;
反应条件
1.1: dichloro(cycloocta-1,5-diene)palladium(II); 9,9-dimethyl-4,5-bis(diphenyl-phosphino)xanthene; magnesium chloride; triethylamine / 1,4-dioxane / 80 °C / |Glovebox; |Inert atmosphere 1.2: 80 °C / |Glovebox; |Inert atmosphere 1.3: 18 h / 80 °C 2.1: hydrogenchloride / water / 1 h / 80 °C View Scheme
参考文献
Chemistry - A European Journal, , vol. 19, # 52 p. 17687 - 17691
