in not given
react. with H3PO2 under pptn. of red P forming POCl3, PCl3 and HCl;;
参考文献
Geuther, A.
Jena. Z. Med. Naturwiss., 1873 , vol. 7, p. 380 - 390
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Geuther, A.
J. prakt. Chem. (2), 1874 , vol. 8, p. 359 - 372
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Gmelin Handbook: P: MVol.C, 193, page 443 - 445
in not given
byproducts: H2O, phosphorus hydrides; react. of PCl3 with concd. H3PO2; formation of P4O, H3PO3, H3PO4 and HCl; by-reaction of H3PO2 forming H3PO4, H3PO3, H2O and P2H4; decompn. of P2H4 with HCl forming gaseous and solid phosphorus hydrides and amorphous P;;
参考文献
Michaelis, A.; Pitsch, M.
Liebigs Annalen der Chemie, 1900 , vol. 310, p. 45 - 74
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Gmelin Handbook: P: MVol.C, 185, page 427 - 429
KOBr3 in sulfuric acid
byproducts: Br2; oxidation on heating a sulfuric soln. of H3PO2 with KOBr3; induction period shortened by HCl, Na2S2O3, NH4CNS Na2S4O6, KBr and colloidal S, induction period extended by H2SO4, sulfate, chloride, nitrate, citrate, tartrates of alkali and albumin;;
参考文献
Sen, B. N.
Collection of Czechoslovak Chemical Communications, 1938 , vol. 10, p. 321 - 329
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Gmelin Handbook: P: MVol.C, 52, page 109 - 112
methyltrioxorhenium (VII) in water
Kinetics; byproducts: t-BuOCH3, t-BuOOCH3, CH3OH; 0.1 M CF3SO3Na, 22.5°C; further byproduct: Me2CO; not isolated, reaction followed by (1)H-NMR spectroscopy;
参考文献
Brittingham, Kimberly A.; Espenson, James H.
Inorganic Chemistry, 1999 , vol. 38, # 4 p. 744 - 750
