2,3-二氢-3,6-二甲基-1H-环戊并[a]蒽合成路线 （共 13 条）
反应条件
1: H2 / Pd-C / ethyl acetate
3: H2 / Pt / acetic acid
4: Pd-C / 320 °C
View Scheme
参考文献
Burgstahler,A.W.; Kulier,C.P.
Journal of Organic Chemistry, 1965 , vol. 30, p. 4384 - 4387
反应条件
1: (bromination)
2: (i) NaOEt, (ii) /BRN= 971015/
3: (i) aq. KOH, (ii) H2O, (heating)
4: SOCl2
5: AlCl3
7: H2 / PtO2
8: (i) EtMgI, (ii) /BRN= 118515/
9: (i) Raney-Ni, (ii) H2, Cu catalyst
10: ZnCl2
11: MeMgBr
View Scheme
参考文献
Nakazaki,M. et al.
Bulletin of the Chemical Society of Japan, 1961 , vol. 34, p. 1189 - 1194
反应条件
1: AlCl3
3: H2 / PtO2
4: (i) EtMgI, (ii) /BRN= 118515/
5: (i) Raney-Ni, (ii) H2, Cu catalyst
6: ZnCl2
7: MeMgBr
View Scheme
参考文献
Nakazaki,M. et al.
Bulletin of the Chemical Society of Japan, 1961 , vol. 34, p. 1189 - 1194
反应条件
1: (i) aq. KOH, (ii) H2O, (heating)
2: SOCl2
3: AlCl3
5: H2 / PtO2
6: (i) EtMgI, (ii) /BRN= 118515/
7: (i) Raney-Ni, (ii) H2, Cu catalyst
8: ZnCl2
9: MeMgBr
View Scheme
参考文献
Nakazaki,M. et al.
Bulletin of the Chemical Society of Japan, 1961 , vol. 34, p. 1189 - 1194
反应条件
2: H2 / PtO2
3: (i) EtMgI, (ii) /BRN= 118515/
4: (i) Raney-Ni, (ii) H2, Cu catalyst
5: ZnCl2
6: MeMgBr
View Scheme
参考文献
Nakazaki,M. et al.
Bulletin of the Chemical Society of Japan, 1961 , vol. 34, p. 1189 - 1194
反应条件
1: SOCl2
2: AlCl3
4: H2 / PtO2
5: (i) EtMgI, (ii) /BRN= 118515/
6: (i) Raney-Ni, (ii) H2, Cu catalyst
7: ZnCl2
8: MeMgBr
View Scheme
参考文献
Nakazaki,M. et al.
Bulletin of the Chemical Society of Japan, 1961 , vol. 34, p. 1189 - 1194
反应条件
1: (i) NaOEt, (ii) /BRN= 971015/
2: (i) aq. KOH, (ii) H2O, (heating)
3: SOCl2
4: AlCl3
6: H2 / PtO2
7: (i) EtMgI, (ii) /BRN= 118515/
8: (i) Raney-Ni, (ii) H2, Cu catalyst
9: ZnCl2
10: MeMgBr
View Scheme
参考文献
Nakazaki,M. et al.
Bulletin of the Chemical Society of Japan, 1961 , vol. 34, p. 1189 - 1194
反应条件
hydrogenchloride; Zn–Hg amalgam; toluene
参考文献
Nakazaki; Isoe
Bulletin of the Chemical Society of Japan, 1959 , vol. 32, p. 1202,1209
反应条件
1: (i) EtMgI, (ii) /BRN= 118515/
2: (i) Raney-Ni, (ii) H2, Cu catalyst
3: ZnCl2
4: MeMgBr
View Scheme
参考文献
Nakazaki,M. et al.
Bulletin of the Chemical Society of Japan, 1961 , vol. 34, p. 1189 - 1194
反应条件
1: MeMgBr
View Scheme
参考文献
Nakazaki,M. et al.
Bulletin of the Chemical Society of Japan, 1961 , vol. 34, p. 1189 - 1194
