甲基4,6-O-异亚丙基吡喃己糖苷合成路线 （共 9 条）
反应条件
pyridinium p-toluenesulfonate in N,N-dimethyl-formamide; acetone T=5°C; 48 h;
参考文献
Isobe, Minoru; Ichikawa, Yoshiyasu; Kitamura, Masato; Goto, Toshio
Chemistry Letters, 1981 , p. 457 - 460
参考文献
Betaneli, Vitali I.; Ovchinnikov, Michael V.; Backinowsky, Leon V.; Kochetkov, Nikolay K.
Carbohydrate Research, 1980 , vol. 84, p. 211 - 224
反应条件
3-chloro-benzenecarboperoxoic acid T=20°C; 5 h; optical yield given as percent destereoselective reaction;
参考文献
Journal of Organic Chemistry, , vol. 76, # 23 p. 9622 - 9629
反应条件
triethylamine in 1,4-dioxane; benzene T=0°C; 4 h;
参考文献
Betaneli, Vitali I.; Ovchinnikov, Michael V.; Backinowsky, Leon V.; Kochetkov, Nikolay K.
Carbohydrate Research, 1980 , vol. 84, p. 211 - 224
反应条件
pyridine T=25°C; 5 h;
参考文献
Copeland, Christopher; Stick, Robert V.
Australian Journal of Chemistry, 1982 , vol. 35, # 3 p. 581 - 589
反应条件
in tetrahydrofuran 4 h;
参考文献
Patroni, Joseph J.; Skelton, Brian W.; Stick, Robert V.; White, Allan H.
Australian Journal of Chemistry, 1980 , vol. 33, # 5 p. 987 - 999
反应条件
1: 78 percent / tetrahydrofuran / 2 h / Heating 2: 78 percent / propylene oxide, methyl iodide / 14 h / 80 °C View Scheme
参考文献
Patroni, Joseph J.; Skelton, Brian W.; Stick, Robert V.; White, Allan H.
Australian Journal of Chemistry, 1980 , vol. 33, # 5 p. 987 - 999
反应条件
1: 74 percent / triethylamine / benzene; dioxane / 4 h / 0 °C 2: 1.) 90percent trifluoroacetic acid; 2.) sulphuric acid / 1.) ethanol, chloroform, 10 min, room t.; 2.) 4 h, room t. 3: hydrogen bromide, acetic anhydride / acetic acid; H2O; CHCl3 / Ambient temperature View Scheme
参考文献
Betaneli, Vitali I.; Ovchinnikov, Michael V.; Backinowsky, Leon V.; Kochetkov, Nikolay K.
Carbohydrate Research, 1980 , vol. 84, p. 211 - 224
反应条件
1: 74 percent / triethylamine / benzene; dioxane / 4 h / 0 °C 2: 1.) 90percent trifluoroacetic acid; 2.) sulphuric acid / 1.) ethanol, chloroform, 10 min, room t.; 2.) 4 h, room t. View Scheme
参考文献
Betaneli, Vitali I.; Ovchinnikov, Michael V.; Backinowsky, Leon V.; Kochetkov, Nikolay K.
Carbohydrate Research, 1980 , vol. 84, p. 211 - 224
