1: With methyl-diethoxy-silane; Rh(t-Bu-Phebox)(OAc)2(aq) in toluene T=60°C; 2: With potassium fluoride; tetrabutyl ammonium fluoride in tetrahydrofuran; methanol; toluene Further stages.;
1: With methyl-diethoxy-silane; Rh<(S,S)-Phebox-i-Pr>(OAc)2(aq) in toluene T=60°C; 2: With potassium fluoride; tetrabutyl ammonium fluoride in tetrahydrofuran; methanol; toluene Further stages.;
[rhodium(I)(carbonyl)2(acetylacetonate)]; hydrogen; (R,S)-Binaphos in benzene T=40°C; P=76000 Torr; 39 h; Yield given. Yields of byproduct given. Title compound not separated from byproducts;
参考文献
Journal of the American Chemical Society, , vol. 119, # 19 p. 4413 - 4423
