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乙二醇
甲醛
63148-62-9
MDI
丁酮
二甲基亚砜
碳酸氢钠
471-34-1
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乙二醇
甲醛
63148-62-9
MDI
丁酮
二甲基亚砜
碳酸氢钠
471-34-1
6-甲氧基-2-萘乙烯
合成路线
（共 49 条）
63444-51-9
6-甲氧基-2-萘乙烯
→
反应条件
23981-80-8
2-(6-甲氧基-2-萘基)丙酸
反应条件
1: 93 percent / tetrakis(tri-p-tolyl phosphite)nickel(0), tri-p-tolyl phosphite, ionol / toluene 2: 85 percent / KOH, H2O / ethane-1,2-diol / 24 h / 125 °C View Scheme
参考文献
Nugent, William A.; McKinney, Ronald J.
Journal of Organic Chemistry, 1985 , vol. 50, # 25 p. 5370 - 5372
63444-51-9
6-甲氧基-2-萘乙烯
→
反应条件
21388-17-0
6-乙基-2-甲氧基萘
反应条件
C28H18Co(1-)*K(1+)*2C4H10O2; hydrogen in toluene T=20°C; P=1500.15 Torr; 3 h; Reagent/catalyst; chemoselective reaction;
参考文献
Gaertner, Dominik; Welther, Alice; Rad, Babak Rezaei; Wolf, Robert; Von Wangelin, Axel Jacobi
Angewandte Chemie - International Edition, 2014 , vol. 53, # 14 p. 3722 - 3726
Angew. Chem., 2014 , vol. 126, # 14 p. 3796 - 3800,5
201230-82-2
+
63444-51-9
6-甲氧基-2-萘乙烯
→
反应条件
21388-17-0
6-乙基-2-甲氧基萘
+
109057-70-7
+
32305-59-2
+
56800-48-7
反应条件
hydrogen; Rh*carbohydrate diphosphinite in benzene T=60°C; P=124116 Torr; catalyst, solvent, pressure; Product distribution;
参考文献
RajanBabu; Ayers, Timothy A.
Tetrahedron Letters, 1994 , vol. 35, # 25 p. 4295 - 4298
63444-51-9
6-甲氧基-2-萘乙烯
→
反应条件
23979-41-1
(R)-萘普生
反应条件
1.1: (S)-(R)-Josiphos; [Rh(COD)2]BF4 / 1,2-dichloro-ethane / 24 h 2.1: n-BuLi / tetrahydrofuran; hexane / -105 - 20 °C 2.2: aq. NaClO2; KH2PO4 / 2-methyl-propan-2-ol; various solvent(s) / 90 h / 20 °C View Scheme
参考文献
Parrinello, Giovanni; Stille, J. K.
Journal of the American Chemical Society, 1987 , vol. 109, # 23 p. 7122 - 7127
201230-82-2
+
63444-51-9
6-甲氧基-2-萘乙烯
→
反应条件
22204-53-1
萘普生
+
23979-41-1
(R)-萘普生
反应条件
hydrogenchloride; oxygen; (S)-BINOL-phosphoric acid; copper dichloride; palladium dichloride in tetrahydrofuran P=760 Torr; 18 h; Ambient temperature; Yield given. Yields of byproduct given. Title compound not separated from byproducts;
参考文献
Alper, Howard; Hamel, Nathalie
Journal of the American Chemical Society, 1990 , vol. 112, # 7 p. 2803 - 2804
63444-51-9
6-甲氧基-2-萘乙烯
→
反应条件
26159-36-4
萘普索
反应条件
1.1: (S)-(R)-Josiphos; [Rh(COD)2]BF4 / 1,2-dichloro-ethane / 24 h 2.1: n-BuLi / tetrahydrofuran; hexane / -105 - 20 °C 2.2: aq. NaClO2; KH2PO4 / 2-methyl-propan-2-ol; various solvent(s) / 90 h / 20 °C 3.1: borane-dimethyl sulfide complex / diethyl ether / 1 h / 0 - 20 °C View Scheme
参考文献
Crudden, Cathleen M.; Hleba, Yonek B.; Chen, Austin C.
Journal of the American Chemical Society, 2004 , vol. 126, # 30 p. 9200 - 9201
201230-82-2
+
63444-51-9
6-甲氧基-2-萘乙烯
→
反应条件
27602-75-1
6-甲氧基-alpha-甲基-2-萘乙醛
+
109057-70-7
反应条件
hydrogen; αα-TREDIP; tris(allyl)rhodium in dichloromethane 48 h; Yield given. Yields of byproduct given;
参考文献
Kim, Jai Jun; Alper, Howard
Chemical Communications, 2005 , # 24 p. 3059 - 3061
201230-82-2
+
63444-51-9
6-甲氧基-2-萘乙烯
→
反应条件
27602-75-1
6-甲氧基-alpha-甲基-2-萘乙醛
反应条件
[κ2-{3-iPr2P-2-O-indene}Rh(COD)]; hydrogen in tetrahydrofuran T=45°C; P=51716.2 Torr; 12 h; regioselective reaction;
参考文献
Uh, Yoon-Seo; Boyd, Alaina; Little, Vanessa R.; Jessop, Philip G.; Hesp, Kevin D.; Cipot-Wechsler, Judy; Stradiotto, Mark; McDonald, Robert
Journal of Organometallic Chemistry, 2010 , vol. 695, # 15-16 p. 1869 - 1872
67-56-1
甲醇
+
201230-82-2
+
63444-51-9
6-甲氧基-2-萘乙烯
→
反应条件
81623-44-1
+
26159-35-3
(S)-萘普生甲酯
反应条件
(S)-2-dicyclohexylphosphino-2'-methoxy-1,1'-binaphthyl; palladium dichloride in benzene T=40°C; 24 h; Product distribution; Further Variations:ReagentsTemperaturesreaction time;
参考文献
Kawashima, Yasutoyo; Okano, Kentaro; Nozaki, Kyoko; Hiyama, Tamejiro
Bulletin of the Chemical Society of Japan, 2004 , vol. 77, # 2 p. 347 - 355
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