22,29,30-三去甲新何帕-13(18)-烯合成路线 （共 5 条）
参考文献
Dunlap, Norma K.; Sabol, Mark R.; Bauer, Philip E.; Watt, David S.; Reibenspies, Joseph H.; et al.
Journal of Organic Chemistry, 1985 , vol. 50, # 11 p. 1826 - 1829
参考文献
Dunlap, Norma K.; Sabol, Mark R.; Bauer, Philip E.; Watt, David S.; Reibenspies, Joseph H.; et al.
Journal of Organic Chemistry, 1985 , vol. 50, # 11 p. 1826 - 1829
反应条件
1: 58 percent / LiAlH4 / diethyl ether; tetrahydrofuran / 2 h / 0 °C
2: polyphosphoric acid / 1 h / 100 °C
View Scheme
参考文献
Dunlap, Norma K.; Sabol, Mark R.; Bauer, Philip E.; Watt, David S.; Reibenspies, Joseph H.; et al.
Journal of Organic Chemistry, 1985 , vol. 50, # 11 p. 1826 - 1829
反应条件
1: 70 percent / LiAlH4 / diethyl ether; tetrahydrofuran / 2 h / 0 °C
2: 91 percent / polyphosphoric acid / 1 h / 100 °C
View Scheme
参考文献
Dunlap, Norma K.; Sabol, Mark R.; Bauer, Philip E.; Watt, David S.; Reibenspies, Joseph H.; et al.
Journal of Organic Chemistry, 1985 , vol. 50, # 11 p. 1826 - 1829
反应条件
hydrogenchloride; mercury; zinc in toluene
1.5 h; Heating; Yield given. Yields of byproduct given. Title compound not separated from byproducts;
参考文献
Dunlap, Norma K.; Sabol, Mark R.; Bauer, Philip E.; Watt, David S.; Reibenspies, Joseph H.; et al.
Journal of Organic Chemistry, 1985 , vol. 50, # 11 p. 1826 - 1829
