(二苯基甲基)硫代乙酸乙酯合成路线 （共 18 条）
反应条件
1.1: H2SO4; 2-propanol; aq. H2O2 / methanol / 20 °C 2.1: 62.1 g / NaOH; H2O / ethanol / 1 h / 20 °C 3.1: (R)-(+)-α-methylbenzylamine / H2O / Heating 3.2: aq. HCl / pH 2 4.1: 68 percent / K2CO3 / acetone / Heating View Scheme
参考文献
Prisinzano, Thomas; Podobinski, John; Tidgewell, Kevin; Luo, Min; Swenson, Dale
Tetrahedron Asymmetry, 2004 , vol. 15, # 6 p. 1053 - 1058
反应条件
1: sulfuric acid; dihydrogen peroxide / methanol; isopropyl alcohol / 2 h / 20 °C 2: sodium hydroxide / ethanol; water / 2 h / 20 °C 3: ammonium hydroxide / dichloromethane / 2 h / 20 °C View Scheme
参考文献
Jung, Jae-Chul; Lee, Yeonju; Son, Jee-Young; Lim, Eunyoung; Jung, Mankil; Oh, Seikwan
Molecules, 2012 , vol. 17, # 9 p. 10446 - 10458
反应条件
1.1: H2SO4; 2-propanol; aq. H2O2 / methanol / 20 °C 2.1: 62.1 g / NaOH; H2O / ethanol / 1 h / 20 °C 3.1: (R)-(+)-α-methylbenzylamine / H2O / Heating 3.2: aq. HCl / pH 2 View Scheme
参考文献
Prisinzano, Thomas; Podobinski, John; Tidgewell, Kevin; Luo, Min; Swenson, Dale
Tetrahedron Asymmetry, 2004 , vol. 15, # 6 p. 1053 - 1058
反应条件
1: sulfuric acid; dihydrogen peroxide / methanol; isopropyl alcohol / 2 h / 20 °C
2: sodium hydroxide / ethanol; water / 2 h / 20 °C
3: ammonium hydroxide / dichloromethane / 2 h / 20 °C
View Scheme
参考文献
Jung, Jae-Chul; Lee, Yeonju; Son, Jee-Young; Lim, Eunyoung; Jung, Mankil; Oh, Seikwan
Molecules, 2012 , vol. 17, # 9 p. 10446 - 10458
反应条件
1: sulfuric acid; dihydrogen peroxide / methanol; isopropyl alcohol / 2 h / 20 °C
2: sodium hydroxide / ethanol; water / 2 h / 20 °C
3: ammonium hydroxide / dichloromethane / 2 h / 20 °C
View Scheme
参考文献
Jung, Jae-Chul; Lee, Yeonju; Son, Jee-Young; Lim, Eunyoung; Jung, Mankil; Oh, Seikwan
Molecules, 2012 , vol. 17, # 9 p. 10446 - 10458
反应条件
sulfuric acid; dihydrogen peroxide; isopropyl alcohol in methanol
T=20°C;
参考文献
Jung, Jae-Chul; Lee, Yeonju; Son, Jee-Young; Lim, Eunyoung; Jung, Mankil; Oh, Seikwan
Molecules, 2012 , vol. 17, # 9 p. 10446 - 10458
反应条件
1.1: sulfuric acid; dihydrogen peroxide / methanol; isopropyl alcohol / 2 h / 20 °C
2.1: sodium hydroxide / ethanol; water / 2 h / 20 °C
3.1: benzotriazol-1-ol; 1-ethyl-(3-(3-dimethylamino)propyl)-carbodiimide hydrochloride / N,N-dimethyl-formamide / 0.5 h / 20 °C
3.2: 1 h / 20 °C
View Scheme
参考文献
Jung, Jae-Chul; Lee, Yeonju; Son, Jee-Young; Lim, Eunyoung; Jung, Mankil; Oh, Seikwan
Molecules, 2012 , vol. 17, # 9 p. 10446 - 10458
反应条件
potassium hydroxide; hydroxylamine hydrochloride in methanol
0.25 h;
参考文献
Prisinzano, Thomas; Podobinski, John; Tidgewell, Kevin; Luo, Min; Swenson, Dale
Tetrahedron Asymmetry, 2004 , vol. 15, # 6 p. 1053 - 1058
