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乙二醇
甲醛
63148-62-9
MDI
丁酮
二甲基亚砜
碳酸氢钠
471-34-1
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乙二醇
甲醛
63148-62-9
MDI
丁酮
二甲基亚砜
碳酸氢钠
471-34-1
4-硝基碘苯
合成路线
(共 886 条)
636-98-6
4-硝基碘苯
+
754-06-3
+
33377-47-8
→
反应条件
100-13-0
4-硝基苯乙烯
反应条件
in N,N,N',N',N'',N''-hexamethylphosphoric triamide T=10°C; 0.25 h; Product distribution;
参考文献
Journal of Organic Chemistry USSR (English Translation), , vol. 20, # 3 p. 411 - 417
Zhurnal Organicheskoi Khimii, , vol. 20, # 3 p. 457 - 464
636-98-6
4-硝基碘苯
+
86-74-8
咔唑
→
反应条件
16982-76-6
9-(4-硝基苯基)-9H-咔唑
反应条件
potassium phosphate; (1S,2S)-1,2-diaminocyclohexane; copper(l) iodide in 1,4-dioxane Ullmann coupling; 24 h; Heating;
参考文献
Wang, Hui; Ryu, Jeong-Tak; Kim, Dong Uk; Han, Yoon Soo; Park, Lee Soon; Cho, Ho-Young; Lee, Sam-Jong; Kwon, Younghwan
Molecular Crystals and Liquid Crystals, 2007 , vol. 471, # 1 p. 279 - 291
636-98-6
4-硝基碘苯
+
143360-89-8
→
反应条件
1741-96-4
反应条件
potassium carbonate in acetonitrile T=110°C; 4 h;
参考文献
Bernini, Roberta; Cacchi, Sandro; Fabrizi, Giancarlo; Forte, Giovanni; Petrucci, Francesco; Prastaro, Alessandro; Niembro, Sandra; Shafir, Alexandr; Vallribera, Adelina
Green Chemistry, 2010 , vol. 12, # 1 p. 150 - 158
636-98-6
4-硝基碘苯
+
111-70-6
→
反应条件
13565-36-1
+
39905-44-7
反应条件
caesium carbonate; [Cu8(S2P(OiPr)2)6(μ8-Cl)][PF6] T=110°C; 11 h; Title compound not separated from byproducts;
参考文献
Manbeck, Gerald F.; Lipman, Adam J.; Stockland Jr., Robert A.; Freidl, Adrienne L.; Hasler, Amy F.; Stone, Joshua J.; Guzei, Ilia A.
Journal of Organic Chemistry, 2005 , vol. 70, # 1 p. 244 - 250
636-98-6
4-硝基碘苯
+
344-04-7
→
反应条件
14743-50-1
反应条件
1-butyl-2,2'-bipyridinium bis(trifluoromethanesulfonyl)amide; copper T=75°C; 20 h;
参考文献
Xiao, Ji-Chang; Ye, Chengfeng; Shreeve, Jean'ne M.
Organic Letters, 2005 , vol. 7, # 10 p. 1963 - 1965
636-98-6
4-硝基碘苯
+
58521-27-0
→
反应条件
14743-50-1
反应条件
copper(l) iodide in diethylene glycol dimethyl ether T=130°C; 24 h; Inert atmosphere;
参考文献
Shang, Rui; Fu, Yao; Wang, Yan; Xu, Qing; Yu, Hai-Zhu; Liu, Lei
Angewandte Chemie - International Edition, 2009 , vol. 48, # 49 p. 9350 - 9354
636-98-6
4-硝基碘苯
+
1582-24-7
→
反应条件
14743-50-1
反应条件
1: pentafluorophenyldihydroxyborane With KHF2 in methanol; water T=20°C; 4 h; 2: para-nitro iodo-benzene With silver(l) oxide; bis-triphenylphosphine-palladium(II) chloride in toluene T=100°C; Suzuki-Miyaura cross-coupling; 8 h; Further stages.;
参考文献
Adonin, Nicolay Yu.; Babushkin, Dmitrii E.; Parmon, Valentin N.; Bardin, Vadim V.; Kostin, Gennadiy A.; Mashukov, Vasiliy I.; Frohn, Hermann-Josef
Tetrahedron, 2008 , vol. 64, # 25 p. 5920 - 5924
636-98-6
4-硝基碘苯
→
反应条件
14743-50-1
反应条件
potassium carbonate; triphenylphosphine; silver(l) oxide; palladium diacetate in toluene T=100°C; 3 h;
参考文献
Frohn; Adonin; Bardin; Starichenko
Tetrahedron Letters, 2002 , vol. 43, # 45 p. 8111 - 8114
636-98-6
4-硝基碘苯
+
363-72-4
→
反应条件
14743-50-1
反应条件
palladium diacetate; triphenylphosphine; silver carbonate in water T=70°C; 24 h; Inert atmosphere;
参考文献
Chen, Fei; Min, Qiao-Qiao; Zhang, Xingang
Journal of Organic Chemistry, 2012 , vol. 77, # 6 p. 2992 - 2998
636-98-6
4-硝基碘苯
+
10387-40-3
→
反应条件
15119-62-7
反应条件
copper(l) iodide; 1,10-phenanthroline in toluene T=100°C; 24 h; Schlenk techniqueInert atmosphere;
参考文献
Soria-Castro, Silvia M.; Penenory, Alicia B.
Beilstein Journal of Organic Chemistry, 2013 , vol. 9, p. 467 - 475
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