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结构式
乙二醇
甲醛
63148-62-9
MDI
丁酮
二甲基亚砜
碳酸氢钠
471-34-1
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乙二醇
甲醛
63148-62-9
MDI
丁酮
二甲基亚砜
碳酸氢钠
471-34-1
4-甲氧基苯乙烯
合成路线
(共 543 条)
637-69-4
4-甲氧基苯乙烯
+
2039-82-9
4-溴苯乙烯
→
反应条件
4705-34-4
4,4'-二甲氧基芪
+
18869-30-2
4,4'-二溴-反-芪
+
58358-51-3
反应条件
RuCl2(p-cymene)[1,3-(Mes)2-imidazol-2-ylidene] in toluene T=80°C; 24 h;
参考文献
Lo, Cheikh; Cariou, Renan; Fischmeister, Cedric; Dixneuf, Pierre H.
Advanced Synthesis and Catalysis, 2007 , vol. 349, # 4-5 p. 546 - 550
637-69-4
4-甲氧基苯乙烯
+
111966-93-9
→
反应条件
4705-34-4
4,4'-二甲氧基芪
+
1256837-50-9
反应条件
(SPY-5-31)-dichloro-(κ2(C,O)-(2-isopropyloxybenzylidene))(1,3-bis(2,4,6-trimethylphenyl)-4,5-dihydroimidazol-2-ylidene)ruthenium in dichloromethane T=25°C; 1 h; Inert atmosphereMolecular sieve; stereoselective reaction;
参考文献
Junker, Christopher S.; Welker, Mark E.; Day, Cynthia S.
Journal of Organic Chemistry, 2010 , vol. 75, # 23 p. 8155 - 8165
637-69-4
4-甲氧基苯乙烯
+
622-97-9
4-甲基苯乙烯
→
反应条件
18869-29-9
4,4'-二甲基-反-二苯乙烯
+
4705-34-4
4,4'-二甲氧基芪
+
17555-94-1
反应条件
Grubb's 2nd generation catalyst in dichloromethane Heating;
参考文献
Velder, Janna; Ritter, Stefanie; Lex, Johann; Schmalz, Hans-Guenther
Synthesis, 2006 , # 2 art. no. T08805SS, p. 273 - 278
637-69-4
4-甲氧基苯乙烯
+
6380-23-0
→
反应条件
4705-34-4
4,4'-二甲氧基芪
+
18513-98-9
+
18513-95-6
反应条件
Grubb's 2nd generation catalyst in dichloromethane Heating;
参考文献
Velder, Janna; Ritter, Stefanie; Lex, Johann; Schmalz, Hans-Guenther
Synthesis, 2006 , # 2 art. no. T08805SS, p. 273 - 278
637-69-4
4-甲氧基苯乙烯
+
40243-87-6
→
反应条件
4705-34-4
4,4'-二甲氧基芪
反应条件
Grubb's 2nd generation catalyst in dichloromethane T=40°C; 1.5 h; Title compound not separated from byproducts;
参考文献
Velder, Janna; Ritter, Stefanie; Lex, Johann; Schmalz, Hans-Guenther
Synthesis, 2006 , # 2 art. no. T08805SS, p. 273 - 278
637-69-4
4-甲氧基苯乙烯
+
62214-38-4
→
反应条件
4705-34-4
4,4'-二甲氧基芪
+
53777-24-5
反应条件
Grubb's 2nd generation catalyst in dichloromethane T=40°C; 18 h;
参考文献
Nagarapu, Lingaiah; Paparaju, Venkateswarlu; Satyender, Apuri
Bioorganic and Medicinal Chemistry Letters, 2008 , vol. 18, # 7 p. 2351 - 2354
637-69-4
4-甲氧基苯乙烯
+
2628-16-2
→
反应条件
4705-34-4
4,4'-二甲氧基芪
+
47241-75-8
反应条件
RuCl2(=CHPh)[1,3-ImH2]P(Cy)3 in dichloromethane T=40°C; 2 h;
参考文献
Chang, Sukbok; Na, Youngim; Shin, Hyun Jung; Choi, Eunjung; Jeong, Lak Shin
Tetrahedron Letters, 2002 , vol. 43, # 41 p. 7445 - 7448
637-69-4
4-甲氧基苯乙烯
+
623-12-1
→
反应条件
4356-69-8
+
4705-34-4
4,4'-二甲氧基芪
反应条件
4-MeO-dppp; palladium diacetate; ethylene glycol; potassium hydroxide T=145°C; Heck reaction; 10 h; Inert atmosphere; regioselective reaction;
参考文献
Ruan, Jiwu; Iggo, Jonathan A.; Berry, Neil G.; Xiao, Jianliang
Journal of the American Chemical Society, 2010 , vol. 132, # 46 p. 16689 - 16699
637-69-4
4-甲氧基苯乙烯
→
反应条件
91517-26-9
反应条件
1: HgO*2HBF4 / tetrahydrofuran / 6 h / 70 °C / |Inert atmosphere 2: palladium on activated charcoal; hydrogen / methanol / 4 h View Scheme
参考文献
Kour, Harpreet; Paul, Satya; Singh, Parvinder Pal; Gupta, Monika; Gupta, Rajive
Tetrahedron Letters, 2013 , vol. 54, # 8 p. 761 - 764
637-69-4
4-甲氧基苯乙烯
+
1384879-87-1
→
反应条件
948-03-8
+
132312-99-3
反应条件
palladium (II) trifluoroacetate; copper diacetate in 1,2-dichloro-ethane T=100°C; 8 h;
参考文献
Journal of the American Chemical Society, , vol. 134, # 28 p. 11308 - 11311
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